On the origin of oxygen in Re6(μ-O)12 core in cubo-octahedral hexanuclear rhenium clusters

被引：3
|
作者：
Krawczyk, Marta S. [1 ]
Krawczyk, Monika K. [1 ]
Siczek, Milosz [1 ]
Lis, Tadeusz [1 ]
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
POLYHEDRON | 2015年 / 97卷
关键词：
Hexanuclear rhenium complex; Cluster; Oxidocomplex; Crystal structure; O-18; isotope; LINDQVIST; HYDROGEN;
D O I：
10.1016/j.poly.2015.05.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The origin of oxygen atoms in oxido-bridged cubo-octahedral hexanuclear rhenium clusters [Re-6(mu-O)(12)L-6](+) (L - aromatic amine) has been investigated thoroughly. We confirmed that water is a crucial agent in the creation of the Re-6(mu-O)(12) core. The reaction of ReI3 with (H2O)-O-18 and 3-methylpyridine was carried out resulting in the formation of [Re-6(mu-O-18)(12)(3-Mepy)(6)]I complex. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：248 / 252
页数：5
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