On the origin of oxygen in Re6(μ-O)12 core in cubo-octahedral hexanuclear rhenium clusters

被引：3
|
作者：
Krawczyk, Marta S. [1 ]
Krawczyk, Monika K. [1 ]
Siczek, Milosz [1 ]
Lis, Tadeusz [1 ]
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
POLYHEDRON | 2015年 / 97卷
关键词：
Hexanuclear rhenium complex; Cluster; Oxidocomplex; Crystal structure; O-18; isotope; LINDQVIST; HYDROGEN;
D O I：
10.1016/j.poly.2015.05.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The origin of oxygen atoms in oxido-bridged cubo-octahedral hexanuclear rhenium clusters [Re-6(mu-O)(12)L-6](+) (L - aromatic amine) has been investigated thoroughly. We confirmed that water is a crucial agent in the creation of the Re-6(mu-O)(12) core. The reaction of ReI3 with (H2O)-O-18 and 3-methylpyridine was carried out resulting in the formation of [Re-6(mu-O-18)(12)(3-Mepy)(6)]I complex. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：248 / 252
页数：5
相关论文
共 50 条
  • [31] Tetrameric arrays of the [Re6(μ3-Se)8]2+ clusters supported by a porphyrin core:: synthesis, characterization, and electrochemical studies
    Roland, BK
    Flora, WH
    Armstrong, NR
    Zheng, ZP
    COMPTES RENDUS CHIMIE, 2005, 8 (11-12) : 1798 - 1807
  • [32] Plutonium(IV) Cluster with a Hexanuclear [Pu6(OH)4O4]12+ Core
    Knope, Karah E.
    Soderholm, L.
    INORGANIC CHEMISTRY, 2013, 52 (12) : 6770 - 6772
  • [33] Routes to metallodendrimers of the [Re6(μ3-Se)8]2+ core-containing clusters (vol 124, pg 6234, 2002)
    Roland, BK
    Carter, C
    Zheng, ZP
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) : 9955 - 9955
  • [34] [NBun4]4[(Re6S5OCl7)2O], an oxo-bridged siamese twin cluster of two hexanuclear oxochalcohalide rhenium clusters
    Simon, F
    Boubekeur, K
    Gabriel, JCP
    Batail, P
    CHEMICAL COMMUNICATIONS, 1998, (07) : 845 - 846
  • [35] Novel concentration-driven structural interconversion in shape-specific solids supported by the octahedral [Re6(μ3-Se)8]2+ cluster core
    Selby, HD
    Orto, P
    Carducci, MD
    Zheng, ZP
    INORGANIC CHEMISTRY, 2002, 41 (24) : 6175 - 6177
  • [36] Synthesis and structural characterization of labile alcohol solvates of the [Re6 (μ3-SE)8]2+ core-containing clusters.
    Ferris, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U470 - U470
  • [37] Singlet Oxygen Production and Biological Activity of Hexanuclear Chalcocyanide Rhenium Cluster Complexes [{Re6Q8}(CN)6]4- (Q = S, Se, Te)
    Solovieva, Anastasiya O.
    Kirakci, Kaplan
    Ivanov, Anton A.
    Kubat, Pavel
    Poznaogova, Tatiana N.
    Miroshnichenko, Svetlana M.
    Vorontsova, Elena V.
    Chechushkov, Anton V.
    Trifonova, Kristina E.
    Fufaeva, Maria S.
    Kretov, Evgeniy I.
    Mironov, Yuri V.
    Poveshchenko, Alexander F.
    Lang, Kamil
    Shestopalov, Michael A.
    INORGANIC CHEMISTRY, 2017, 56 (21) : 13491 - 13499
  • [38] Octahedral clusters of rhenium tellurobromide: Syntheses and crystal structures of [NPr4]2[Re6Te6Br8] and [PPh4][Re6Te5Br9]
    Y. V. Mironov
    V. E. Fedorov
    M. A. Pell
    J. A. Ibers
    Journal of Structural Chemistry, 1998, 39 : 609 - 614
  • [39] Octahedral clusters of rhenium tellurobromide:: Syntheses and crystal structures of [NPr4]2[Re6Te6Br8] and [PPh4][Re6Te5Br9]
    Mironov, YV
    Fedorov, VE
    Pell, MA
    Ibers, JA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1998, 39 (04) : 609 - 614
  • [40] NEW QUATERNARY RHENIUM CHALCOHALIDES WITH OCTAHEDRAL RE-6 CLUSTERS - MRE6Y5X9 (M = UNIVALENT CATION, X = HALOGEN, Y = CHALCOGEN)
    PERRIN, A
    LEDUC, L
    POTEL, M
    SERGENT, M
    MATERIALS RESEARCH BULLETIN, 1990, 25 (10) : 1227 - 1234
12345