On the origin of oxygen in Re6(μ-O)12 core in cubo-octahedral hexanuclear rhenium clusters

被引：3

作者：

Krawczyk, Marta S. ^{[1
]}

Krawczyk, Monika K. ^{[1
]}

Siczek, Milosz ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

POLYHEDRON | 2015年 / 97卷

关键词：

Hexanuclear rhenium complex; Cluster; Oxidocomplex; Crystal structure; O-18; isotope; LINDQVIST; HYDROGEN;

D O I：

10.1016/j.poly.2015.05.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The origin of oxygen atoms in oxido-bridged cubo-octahedral hexanuclear rhenium clusters [Re-6(mu-O)(12)L-6](+) (L - aromatic amine) has been investigated thoroughly. We confirmed that water is a crucial agent in the creation of the Re-6(mu-O)(12) core. The reaction of ReI3 with (H2O)-O-18 and 3-methylpyridine was carried out resulting in the formation of [Re-6(mu-O-18)(12)(3-Mepy)(6)]I complex. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：248 / 252

页数：5

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