Few-Layer Borocarbonitride Nanosheets: Platinum-Free Catalyst for the Oxygen Reduction Reaction

被引：28
|
作者：
Moses, Kota [2 ]
Kiran, Vankayala [1 ]
Sampath, S. [1 ]
Rao, C. N. R. [2 ,3 ]
机构：
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, Mat Res Ctr, Bangalore 560012, Karnataka, India
[3] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 03期
关键词：
doping; layered compounds; nanostructures; nitrides; reduction; METAL-FREE ELECTROCATALYSTS; CARBON NANOTUBE ARRAYS; DOPED GRAPHENE; NITROGEN; NANOPARTICLES; PERFORMANCE; PHOSPHORUS; SULFUR;
D O I：
10.1002/asia.201301471
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present study demonstrates the use of few-layer borocarbonitride nanosheets synthesized by a simple method as non-platinum cathode catalysts for the oxygen reduction reaction (ORR) in alkaline medium. Composition-dependent ORR activity is observed and the best performance was found when the composition was carbon-rich. Mechanistic aspects reveal that ORR follows the 4e(-) pathway with kinetic parameters comparable to those of the commercial Pt/C catalyst. Excellent methanol tolerance is observed with the BCN nanosheets unlike with Pt/C.
引用
收藏
页码：838 / 843
页数：6
相关论文
共 50 条
  • [31] Synthesis and electrochemical property of few-layer molybdenum disulfide nanosheets
    Fu, Yanjue
    Wang, Chunrui
    Wang, Linlin
    Peng, Xia
    Wu, Binhe
    Sun, Xingqu
    Chen, Xiaoshuang
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2016, 55 (12)
  • [32] Graphene Supported Platinum Nanoparticles as Catalyst for Oxygen Reduction Reaction
    Zhang Wenyu
    Wang Zhixin
    Shen Yan
    Xi Muyao
    Chu Xuebin
    Xi Chunyu
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2015, 31 (06) : 1007 - 1011
  • [33] Graphene supported platinum nanoparticles as catalyst for oxygen reduction reaction
    Wenyu Zhang
    Zhixin Wang
    Yan Shen
    Muyao Xi
    Xuebin Chu
    Chunyu Xi
    Chemical Research in Chinese Universities, 2015, 31 : 1007 - 1011
  • [34] Stability studies of few-layer InSe nanosheets by Raman spectroscopy
    Xie, Qiyun
    Hu, Chengxiang
    Xu, Lihuan
    Chen, Limin
    Wang, Wei
    Yin, Handi
    Cheng, Guofeng
    Ai, Xiaoqian
    SOLID STATE COMMUNICATIONS, 2021, 336
  • [35] A CoFe2 Alloy-Functionalized Few-Layer Graphene Sheet Nanocomposite as an Electrocatalyst of the Oxygen Reduction Reaction
    Guo, Xiqiong
    Yuan, Fangying
    Wang, Peixi
    Li, Runqiu
    Zheng, Hui
    CHEMISTRYSELECT, 2023, 8 (33):
  • [36] Oxygen reduction reaction at few-layer graphene structures obtained via plasma-assisted electrochemical exfoliation of graphite
    Vasiliev, V. P.
    Kotkin, A. S.
    Kochergin, V. K.
    Manzhos, R. A.
    Krivenko, A. G.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2019, 851
  • [37] Multicomponent platinum-free nanoporous Pd-based alloy as an active and methanol-tolerant electrocatalyst for the oxygen reduction reaction
    Xiaoting Chen
    Conghui Si
    Ying Wang
    Yi Ding
    Zhonghua Zhang
    Nano Research, 2016, 9 : 1831 - 1843
  • [38] A platinum-free cathode catalyst supported on nanosized titanium dioxide
    A. Yu. Tsivadze
    O. V. Lozovaya
    M. R. Tarasevich
    V. A. Bogdanovskaya
    I. Yu. Pinus
    Doklady Physical Chemistry, 2011, 438
  • [39] Multicomponent platinum-free nanoporous Pd-based alloy as an active and methanol-tolerant electrocatalyst for the oxygen reduction reaction
    Chen, Xiaoting
    Si, Conghui
    Wang, Ying
    Ding, Yi
    Zhang, Zhonghua
    NANO RESEARCH, 2016, 9 (06) : 1831 - 1843
  • [40] A platinum-free cathode catalyst supported on nanosized titanium dioxide
    Tsivadze, A. Yu.
    Lozovaya, O. V.
    Tarasevich, M. R.
    Bogdanovskaya, V. A.
    Pinus, I. Yu.
    DOKLADY PHYSICAL CHEMISTRY, 2011, 438 : 86 - 89
12345