Breathing Some New Life into an Old Topic: Chalcogen-Nitrogen π-Heterocycles as Electron Acceptors

被引：89
|
作者：
Lonchakov, Anton V. [1 ,2 ]
Rakitin, Oleg A. [3 ]
Gritsan, Nina P. [1 ,2 ]
Zibarev, Andrey V. [2 ,4 ]
机构：
[1] Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
[2] Natl Res Univ Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Inst Organ Chem, Moscow 119991, Russia
[4] Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia
来源：
MOLECULES | 2013年 / 18卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
organic electron acceptors; radical-anion salts; charge-transfer complexes; SPIN-RESONANCE-SPECTRA; CHARGE-TRANSFER COMPLEXES; X-RAY-STRUCTURE; RADICAL-ANION; CRYSTAL-STRUCTURES; THIAZYL RADICALS; 1,2,5-CHALCOGENADIAZOLE DERIVATIVES; PENTACARBONYL COMPLEXES; ORGANIC SEMICONDUCTORS; POLYNUCLEAR MANGANESE;
D O I：
10.3390/molecules18089850
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Recent progress in the design, synthesis and characterization of chalcogen-nitrogen pi-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts-candidate building blocks of molecule-based electrical and magnetic functional materials.
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页码：9850 / 9900
页数：51
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