Breathing Some New Life into an Old Topic: Chalcogen-Nitrogen π-Heterocycles as Electron Acceptors

被引：89

作者：

Lonchakov, Anton V. ^{[1
,2
]}

Rakitin, Oleg A. ^{[3
]}

Gritsan, Nina P. ^{[1
,2
]}

Zibarev, Andrey V. ^{[2
,4
]}

机构：

[1] Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia

[2] Natl Res Univ Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Inst Organ Chem, Moscow 119991, Russia

[4] Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia

来源：

MOLECULES | 2013年 / 18卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

organic electron acceptors; radical-anion salts; charge-transfer complexes; SPIN-RESONANCE-SPECTRA; CHARGE-TRANSFER COMPLEXES; X-RAY-STRUCTURE; RADICAL-ANION; CRYSTAL-STRUCTURES; THIAZYL RADICALS; 1,2,5-CHALCOGENADIAZOLE DERIVATIVES; PENTACARBONYL COMPLEXES; ORGANIC SEMICONDUCTORS; POLYNUCLEAR MANGANESE;

D O I：

10.3390/molecules18089850

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Recent progress in the design, synthesis and characterization of chalcogen-nitrogen pi-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts-candidate building blocks of molecule-based electrical and magnetic functional materials.

引用

页码：9850 / 9900

页数：51

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