Synthesis of a novel C3-symmetric arsine and its application in stereoselective cyclopropanation of electron-deficient olefins

被引：7

作者：

Wang, Changqing ^{[1
]}

机构：

[1] Yichun Univ, Coll Chem & Bioengn, Key Lab Jiangxi Univ Appl Chem & Chem Biol, Yichun 336000, Peoples R China

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 51期

关键词：

Arsine; One-pot; Cyclopropanation; Stereoselectivity; Ylide; DERIVATIVES; COMPLEXITY; SYMMETRY; DESIGN;

D O I：

10.1016/j.tetlet.2012.10.070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel C-3-symmetric arsine was synthesized from p-arsanilic acid in three steps. It was employed in the one-pot cyclopropanation of olefins with carbonyl-stabilized arsonium ylides formed in situ from methyl bromoacetate in the presence of NaHCO3. This new arsine demonstrates good stereoselectivity and activity in the one-pot cyclopropanation of arylidenemalononitrile. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：7003 / 7005

页数：3

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