The 'Trinity' helix:: synthesis and structural characterisation of a C3-symmetric tris-bidentate ligand and its coordination to Ag(I)

被引：23

作者：

Conerney, B ^{[1
]}

Jensen, P ^{[1
]}

Kruger, PE ^{[1
]}

MacGloinn, C ^{[1
]}

机构：

[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 11期

关键词：

D O I：

10.1039/b302652c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structural characterisation of a novel C-3-symmetric tris-bidentate ligand, L, featuring a triphenylamine core appended by pyridylimine coordination sites is reported: H-1 NMR compleximetric titration studies with Ag(I) and ESMS indicate the presence of [Ag3L2](3+) species in solution, consistent with the formation of a trinuclear double helicate complex: the Trinity helix.

引用

页码：1274 / 1275

页数：2

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