Protodecarboxylation of benzoic acids under radical conditions

被引：96
|
作者：
Seo, Sangwon [1 ]
Taylor, John B. [2 ]
Greaney, Michael F. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[2] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 66期
基金：
英国工程与自然科学研究理事会;
关键词：
COUPLING REACTIONS; CARBOXYLIC-ACIDS; DECARBOXYLATION; ARYLATION; KINETICS;
D O I：
10.1039/c2cc33306f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new approach to protodecarboxylation is described that enhances the substrate scope for benzoic acids. The reaction uses oxidative radical conditions to decarboxylate a variety of acids in acetonitrile.
引用
收藏
页码：8270 / 8272
页数：3
相关论文
共 50 条
  • [41] Synthesis of N-substituted thioamides of benzoic acids under microwave activation
    S. D. Fazylov
    O. A. Nurkenov
    Zh. S. Akhmetkarimova
    D. R. Zhienbaeva
    Russian Journal of General Chemistry, 2012, 82 : 781 - 782
  • [42] (HYDROXYMERCURI)-BENZOIC AND -SALICYLIC ACIDS
    SAIKINA, MK
    LAVRUKHI.LV
    TOROPOVA, VF
    JOURNAL OF GENERAL CHEMISTRY USSR, 1968, 38 (04): : 732 - &
  • [43] Decarboxylative Hydroxylation of Benzoic Acids
    Su, Wanqi
    Xu, Peng
    Ritter, Tobias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (45) : 24012 - 24017
  • [44] BENZOIC-ACID AND HYDROXYLATED BENZOIC-ACIDS IN POLLEN
    FOUNTAIN, DW
    CORNFORD, CA
    SHAW, GJ
    GRANA, 1995, 34 (03) : 213 - 216
  • [45] Interactions of morphine and codeine with benzoic acid and substituted benzoic acids
    Kuila, DK
    Lahiri, SC
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2004, 81 (11) : 928 - 934
  • [46] ESTERS OF BENZOIC AND CHLOROBENZOIC ACIDS
    MONROE, E
    HAND, CR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) : 487 - 488
  • [47] CLEAVAGE OF ANTHRAQUINONES TO BENZOIC ACIDS
    DAVIES, DG
    HODGE, P
    CHEMICAL COMMUNICATIONS, 1968, (16) : 953 - &
  • [48] About the occurrence of benzoic and glucuronic acids in wether urine after feeding with benzoic acids.
    Magnus-Levy, A
    BIOCHEMISCHE ZEITSCHRIFT, 1907, 6 : 502 - 522
  • [49] OH RADICAL-INDUCED MAIN-CHAIN SCISSION OF POLY(RIBONUCLEIC ACIDS) UNDER ANOXIC CONDITIONS
    WASHINO, K
    DENK, O
    SCHNABEL, W
    ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 1983, 38 (1-2): : 100 - 106
  • [50] Rhodium-Catalyzed Intramolecular Acylation of 2-(Indol-1-yl)-benzoic Acids under Redox-Neutral Conditions
    Suzuki, Hirotsugu
    Takemura, Yosuke
    Matsuda, Takanori
    SYNLETT, 2023, 34 (16) : 1894 - 1898
12345