Protodecarboxylation of benzoic acids under radical conditions

被引：96

作者：

Seo, Sangwon ^{[1
]}

Taylor, John B. ^{[2
]}

Greaney, Michael F. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 66期

基金：

英国工程与自然科学研究理事会;

关键词：

COUPLING REACTIONS; CARBOXYLIC-ACIDS; DECARBOXYLATION; ARYLATION; KINETICS;

D O I：

10.1039/c2cc33306f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new approach to protodecarboxylation is described that enhances the substrate scope for benzoic acids. The reaction uses oxidative radical conditions to decarboxylate a variety of acids in acetonitrile.

引用

页码：8270 / 8272

页数：3

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