Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines

被引：16

作者：

Epple, L. ^{[1
]}

Amsharov, K. Yu. ^{[1
]}

Jansen, M. ^{[1
]}

机构：

[1] Max Planck Inst Solid State Res, Stuttgart, Germany

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2009年 / 17卷 / 01期

关键词：

X-ray; single crystal structure; higher fullerenes; porphyrine; ENDOHEDRAL FULLERENE; C-60; C-70; COMPLEXES; CRYSTALS;

D O I：

10.1080/15363830802519420

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two co-crystals of individual isomers of higher fullerenes C76-D2 and C78(2)-C2v with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C78(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice.

引用

页码：67 / 77

页数：11

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