Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines

被引：16
|
作者：
Epple, L. [1 ]
Amsharov, K. Yu. [1 ]
Jansen, M. [1 ]
机构：
[1] Max Planck Inst Solid State Res, Stuttgart, Germany
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2009年 / 17卷 / 01期
关键词：
X-ray; single crystal structure; higher fullerenes; porphyrine; ENDOHEDRAL FULLERENE; C-60; C-70; COMPLEXES; CRYSTALS;
D O I：
10.1080/15363830802519420
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two co-crystals of individual isomers of higher fullerenes C76-D2 and C78(2)-C2v with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C78(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice.
引用
收藏
页码：67 / 77
页数：11
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