Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines

被引：16
|
作者：
Epple, L. [1 ]
Amsharov, K. Yu. [1 ]
Jansen, M. [1 ]
机构：
[1] Max Planck Inst Solid State Res, Stuttgart, Germany
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2009年 / 17卷 / 01期
关键词：
X-ray; single crystal structure; higher fullerenes; porphyrine; ENDOHEDRAL FULLERENE; C-60; C-70; COMPLEXES; CRYSTALS;
D O I：
10.1080/15363830802519420
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two co-crystals of individual isomers of higher fullerenes C76-D2 and C78(2)-C2v with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C78(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice.
引用
收藏
页码：67 / 77
页数：11
相关论文
共 50 条
  • [1] A new method for separating the D3 and C2v isomers of C78
    Han, Ai Hong
    Wakahara, Takatsugu
    Maeda, Yutaka
    Akasaka, Takeshi
    Fujitska, Mamoru
    Ito, Osamu
    Yamamoto, Kazunori
    Kako, Masahiro
    Kobayashi, Kaoru
    Nagase, Shigeru
    NEW JOURNAL OF CHEMISTRY, 2009, 33 (03) : 497 - 500
  • [2] A Fast Route Toward the Preparative Isolation of Fullerene Isomers C78(1) and C78(2)
    Simeonov, Kalin S.
    Amsharov, Konstantin Yu.
    Jansen, Martin
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2009, 17 (04) : 341 - 348
  • [3] C78~n(C2v)的电子结构和UV谱
    吴师
    滕启文
    有机化学, 2004, (07) : 822 - 824+711
  • [4] Electronic structures and UV spectra of C78n(C2v)
    Wu, S
    Teng, QW
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2004, 24 (07) : 822 - 824
  • [5] The IR Spectra, Molar Absorptivity, and Integrated Molar Absorptivity of the C76-D2 and C84-D2:22 Isomers
    Jovanovic, Tamara
    Koruga, Duro
    Jovancicevic, Branimir
    JOURNAL OF NANOMATERIALS, 2017, 2017
  • [6] IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C76-D2 for Its Quantitative and Qualitative Determination
    Jovanovic, Tamara
    Koruga, Djuro
    Mitrovic, Aleksandra
    Stamenkovic, Dragomir
    Devic, Gordana
    JOURNAL OF NANOMATERIALS, 2018, 2018
  • [7] Calculated paramagnetic hyperfine structure of the C2v isomers of Ag3
    Bravo-Vasquez, J.P.
    Arratia-Perez, R.
    Journal of Physical Chemistry, 1994, 98 (22):
  • [8] ELECTRONIC-STRUCTURES OF BIS(BENZENE)CHROMIUM AND THE C2H AND C2V ISOMERS OF BIS(NAPHTHALENE)CHROMIUM
    OSBORNE, JH
    TROGLER, WC
    MORAND, PD
    FRANCIS, CG
    ORGANOMETALLICS, 1987, 6 (01) : 94 - 100
  • [9] Optical excitation and absorption spectra of C2v and D2d isomers of CO4
    Jiang, Chen-Wei
    Xie, Rui-Hua
    Li, Fu-Li
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2008, 63 (3-4): : 170 - 174
  • [10] Excited states and reduced and oxidized forms of C-76(D-2) and C-78(C-2v')
    Guldi, DM
    Liu, D
    Kamat, PV
    JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (35): : 6195 - 6201
12345