Iron-surfactant nanocomposite-catalyzed benzylic oxidation in water

被引:19
|
作者
Szabo, Fruzsina [1 ]
Petho, Balint [1 ]
Gonda, Zsombor [1 ]
Novak, Zoltan [1 ]
机构
[1] Eotvos Lorand Univ, Inst Chem, H-1117 Budapest, Hungary
来源
RSC ADVANCES | 2013年 / 3卷 / 15期
关键词
TERT-BUTYL HYDROPEROXIDE; SATURATED-HYDROCARBONS; ORGANIC-REACTIONS; SELECTIVE OXIDATION; CROSS-COUPLINGS; GIF CHEMISTRY; FUNCTIONALIZATION; ALKANES; KETONES; MECHANISM;
D O I
10.1039/c3ra22856h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Benzylic oxidation in the presence of an iron-surfactant nanocomposite catalyst under aqueous conditions is described. A significant reaction rate acceleration in the presence of anionic surfactants was demonstrated. Several benzylic substrates were efficiently transformed to ketones under mild conditions.
引用
收藏
页码:4903 / 4908
页数:6
相关论文
共 50 条
  • [41] Chromium(VI) oxide-catalyzed benzylic oxidation with periodic acid
    Yamazaki, S
    ORGANIC LETTERS, 1999, 1 (13) : 2129 - 2132
  • [42] Palladium-catalyzed oxidation of primary and secondary allylic and benzylic alcohols
    Peterson, KP
    Larock, RC
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10): : 3185 - 3189
  • [43] Zinc-catalyzed benzylic C-H bond oxidation
    Wu, Xiao-Feng
    TETRAHEDRON LETTERS, 2012, 53 (45) : 6123 - 6126
  • [44] Mild Cu-Catalyzed Oxidation of Benzylic Boronic Esters to Ketones
    Grayson, James D.
    Partridge, Benjamin M.
    ACS CATALYSIS, 2019, 9 (05) : 4296 - 4301
  • [45] Metal catalyzed benzylic oxidation of lignin and lignin models with molecular oxygen
    Chatterjee, Sabornie
    Bozell, Joseph J.
    Murphy, Aaron P.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [46] Benzylic Alcohol Oxidation using Copper Oxide/ZincOxide/Zirconia Nanocomposite Catalysts
    Mokhtar, Mohamed
    Panja, Subir
    Alshehri, Abdulmohsen
    Halawani, Wael
    Maiti, Debabrata
    CHEMISTRY-AN ASIAN JOURNAL, 2023, 18 (07)
  • [47] Silver catalyzed zinc Barbier reaction of benzylic halides in water
    Bieber, LW
    Storch, EC
    Malvestiti, I
    da Silva, MF
    TETRAHEDRON LETTERS, 1998, 39 (51) : 9393 - 9396
  • [48] Oxidation of 3,4-dimethoxybenzyl alcohol in water catalyzed by iron tetrasulfophthalocyanine
    Hampton, KW
    Ford, WT
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) : 167 - 174
  • [50] Fe(III) @g-C3N4 nanocomposite-catalyzed green synthesis of di-indolyloxindole derivatives
    Ali Allahresani
    Bahare Taheri
    M. A. Nasseri
    Research on Chemical Intermediates, 2018, 44 : 6741 - 6751