Iron-surfactant nanocomposite-catalyzed benzylic oxidation in water

被引：19
|
作者：
Szabo, Fruzsina [1 ]
Petho, Balint [1 ]
Gonda, Zsombor [1 ]
Novak, Zoltan [1 ]
机构：
[1] Eotvos Lorand Univ, Inst Chem, H-1117 Budapest, Hungary
来源：
RSC ADVANCES | 2013年 / 3卷 / 15期
关键词：
TERT-BUTYL HYDROPEROXIDE; SATURATED-HYDROCARBONS; ORGANIC-REACTIONS; SELECTIVE OXIDATION; CROSS-COUPLINGS; GIF CHEMISTRY; FUNCTIONALIZATION; ALKANES; KETONES; MECHANISM;
D O I：
10.1039/c3ra22856h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzylic oxidation in the presence of an iron-surfactant nanocomposite catalyst under aqueous conditions is described. A significant reaction rate acceleration in the presence of anionic surfactants was demonstrated. Several benzylic substrates were efficiently transformed to ketones under mild conditions.
引用
收藏
页码：4903 / 4908
页数：6
相关论文
共 50 条
  • [21] Unraveling the Mechanism of Water Oxidation Catalyzed by Nonheme Iron Complexes
    Acuna-Pares, Ferran
    Codola, Zoel
    Costas, Miquel
    Luis, Josep M.
    Lloret-Fillol, Julio
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (19) : 5696 - 5707
  • [22] Water oxidation catalyzed by mononuclear iron and cobalt polypyridine complexes
    Das, Biswanath
    Orthaber, Andreas
    Ott, Sascha
    Thapper, Anders
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2017, 22 : S259 - S259
  • [23] Magnetic g-C3N4 nanocomposite-catalyzed environmentally benign aminolysis of epoxide
    Ahooie, Tahereh Soleymani
    Azizi, Najmedin
    Hashemi, Mohammad Mahmoudi
    Yavari, Issa
    RESEARCH ON CHEMICAL INTERMEDIATES, 2018, 44 (02) : 1425 - 1436
  • [24] Magnetic g-C3N4 nanocomposite-catalyzed environmentally benign aminolysis of epoxide
    Tahereh Soleymani Ahooie
    Najmedin Azizi
    Mohammad Mahmoudi Hashemi
    Issa Yavari
    Research on Chemical Intermediates, 2018, 44 : 1425 - 1436
  • [25] Palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols
    Luo, Fang
    Pan, Changduo
    Cheng, Jiang
    Chen, Fan
    TETRAHEDRON, 2011, 67 (33) : 5878 - 5882
  • [26] Aerobic oxidation of benzylic aldehydes to acids catalyzed by iron (Ⅲ) meso-tetraphenylporphyrin chloride under ambient conditions
    Xian Tai Zhou Hong Bing Ji~* Qiu Lan Yuan Jian Chang Xu Li Xia Pei Le Fu Wang School of Chemical and Energy Engineering
    Chinese Chemical Letters, 2007, (08) : 926 - 928
  • [27] Ruthenium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols
    Zhang, Di
    Pan, Changduo
    CATALYSIS COMMUNICATIONS, 2012, 20 : 41 - 45
  • [28] Electronic, steric, and temperature effects in the Pd(II)-biquinoline catalyzed aerobic oxidation of benzylic alcohols in water
    Buffin, Brian P.
    Belitz, Nadine L.
    Verbeke, Sara L.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 284 (1-2) : 149 - 154
  • [29] Photoactivated and photopassivated benzylic oxidation catalyzed by pristine and oxidized carbons
    Sereda, Grigoriy
    Rajpara, Vikul
    CATALYSIS COMMUNICATIONS, 2011, 12 (07) : 669 - 672
  • [30] COBALT-CATALYZED BENZYLIC OXIDATION WITH MOLECULAR-OXYGEN
    MAIKAP, GC
    GUHATHAKURTA, D
    IQBAL, J
    SYNLETT, 1995, (02) : 189 - 190
12345