Iron-surfactant nanocomposite-catalyzed benzylic oxidation in water

被引：19
|
作者：
Szabo, Fruzsina [1 ]
Petho, Balint [1 ]
Gonda, Zsombor [1 ]
Novak, Zoltan [1 ]
机构：
[1] Eotvos Lorand Univ, Inst Chem, H-1117 Budapest, Hungary
来源：
RSC ADVANCES | 2013年 / 3卷 / 15期
关键词：
TERT-BUTYL HYDROPEROXIDE; SATURATED-HYDROCARBONS; ORGANIC-REACTIONS; SELECTIVE OXIDATION; CROSS-COUPLINGS; GIF CHEMISTRY; FUNCTIONALIZATION; ALKANES; KETONES; MECHANISM;
D O I：
10.1039/c3ra22856h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzylic oxidation in the presence of an iron-surfactant nanocomposite catalyst under aqueous conditions is described. A significant reaction rate acceleration in the presence of anionic surfactants was demonstrated. Several benzylic substrates were efficiently transformed to ketones under mild conditions.
引用
收藏
页码：4903 / 4908
页数：6
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