Manipulating fluorescence characteristics of conjugated fluorescent molecules incorporated into three-dimensional poly(methyl methacrylate) opal photonic crystals

被引：10
|
作者：
Sui, Ning [1 ,3 ]
Wang, Ying-Hui [1 ,2 ]
Song, Yun-Fei [4 ]
Wang, Fu-Yin [1 ]
Ma, Yu-Guang [2 ]
Zhang, Han-Zhuang [1 ]
机构：
[1] Jilin Univ, Coll Phys, Femtosecond Laser Lab, Changchun 130012, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[4] Harbin Inst Technol, Dept Phys, Harbin 150000, Peoples R China
来源：
APPLIED PHYSICS EXPRESS | 2014年 / 7卷 / 02期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
SPONTANEOUS EMISSION; POLYMERS;
D O I：
10.7567/APEX.7.025202
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
We compare the fluorescence characteristics of conjugated molecules (coumarin 6, C-6) in solution, aggregation state, and poly(methyl methacrylate) PMMA opal photonic crystals (PCs), and investigate the manipulation mechanism of PCs on C-6. We find that the PCs effectively inhibit the aggregate-induced fluorescence quenching of C-6 by breaking the intermolecular interaction and manipulate the fluorescence characteristics of C-6 by changing the photonic stop band (PSB). The emission traces of C-6 have been analyzed using the continuous rate distribution model. The control of fluorescence characteristics of C-6 in PCs depends on the mesh microporous structure and the PSB of PCs. (C) 2014 The Japan Society of Applied Physics
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页数：4
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