Manipulating fluorescence characteristics of conjugated fluorescent molecules incorporated into three-dimensional poly(methyl methacrylate) opal photonic crystals

被引：10

作者：

Sui, Ning ^{[1
,3
]}

Wang, Ying-Hui ^{[1
,2
]}

Song, Yun-Fei ^{[4
]}

Wang, Fu-Yin ^{[1
]}

Ma, Yu-Guang ^{[2
]}

Zhang, Han-Zhuang ^{[1
]}

机构：

[1] Jilin Univ, Coll Phys, Femtosecond Laser Lab, Changchun 130012, Peoples R China

[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[4] Harbin Inst Technol, Dept Phys, Harbin 150000, Peoples R China

来源：

APPLIED PHYSICS EXPRESS | 2014年 / 7卷 / 02期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

SPONTANEOUS EMISSION; POLYMERS;

D O I：

10.7567/APEX.7.025202

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We compare the fluorescence characteristics of conjugated molecules (coumarin 6, C-6) in solution, aggregation state, and poly(methyl methacrylate) PMMA opal photonic crystals (PCs), and investigate the manipulation mechanism of PCs on C-6. We find that the PCs effectively inhibit the aggregate-induced fluorescence quenching of C-6 by breaking the intermolecular interaction and manipulate the fluorescence characteristics of C-6 by changing the photonic stop band (PSB). The emission traces of C-6 have been analyzed using the continuous rate distribution model. The control of fluorescence characteristics of C-6 in PCs depends on the mesh microporous structure and the PSB of PCs. (C) 2014 The Japan Society of Applied Physics

引用

页数：4

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