Photoluminescent oxygen sensing using palladium tetrakis(4-carboxyphenyl)porphyrin self-assembled membrane on alumina

被引：24
|
作者：
Amao, Y [1 ]
Asai, K
Okura, I
机构：
[1] Tokyo Inst Technol, Dept Bioengn, Midori Ku, Yokohama, Kanagawa 2268501, Japan
[2] Natl Aerosp Lab, Aerodynam Div, Tokyo 1828522, Japan
来源：
ANALYTICAL COMMUNICATIONS | 1999年 / 36卷 / 05期
关键词：
D O I：
10.1039/a900721k
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An optical oxygen sensor based on the photoluminescent quenching of palladium tetrakis(4-carboxyphenyl)porphyrin (PdTCPP) self-assembled membrane on an alumina plate has been developed. The luminescence intensity of PdTCPP membrane decreased with increase of oxygen concentration, indicating that this membrane is a highly sensitive device for oxygen concentration. The signal changes of this membrane are large enough to allow quantification of oxygen with good sensitivity (I-0/I-100 > 3). The response times of the sensor are 36 s on going from argon to oxygen and 148 s from oxygen to argon. This is a photostable sensing membrane that exhibits minimal decrease (ca 5%) in initial intensity after continuous irradiation for 24 h.
引用
收藏
页码：179 / 180
页数：2
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