Photoluminescent oxygen sensing using palladium tetrakis(4-carboxyphenyl)porphyrin self-assembled membrane on alumina

被引：24

作者：

Amao, Y ^{[1
]}

Asai, K

Okura, I

机构：

[1] Tokyo Inst Technol, Dept Bioengn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

[2] Natl Aerosp Lab, Aerodynam Div, Tokyo 1828522, Japan

来源：

ANALYTICAL COMMUNICATIONS | 1999年 / 36卷 / 05期

关键词：

D O I：

10.1039/a900721k

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An optical oxygen sensor based on the photoluminescent quenching of palladium tetrakis(4-carboxyphenyl)porphyrin (PdTCPP) self-assembled membrane on an alumina plate has been developed. The luminescence intensity of PdTCPP membrane decreased with increase of oxygen concentration, indicating that this membrane is a highly sensitive device for oxygen concentration. The signal changes of this membrane are large enough to allow quantification of oxygen with good sensitivity (I-0/I-100 > 3). The response times of the sensor are 36 s on going from argon to oxygen and 148 s from oxygen to argon. This is a photostable sensing membrane that exhibits minimal decrease (ca 5%) in initial intensity after continuous irradiation for 24 h.

引用

页码：179 / 180

页数：2

共 32 条

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