NCN-Pincer Cobalt Complexes Containing Bis(oxazolinyl)phenyl Ligands

被引：12
|
作者：
Hosokawa, Satomi [1 ]
Ito, Jun-ichi [1 ]
Nishiyama, Hisao [1 ]
机构：
[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 14期
基金：
日本学术振兴会;
关键词：
H BOND ACTIVATION; REGIOSPECIFIC CYCLOMETALATION; STRUCTURAL-CHARACTERIZATION; COORDINATION; ALDEHYDES; ARENES;
D O I：
10.1021/om400450n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We describe the preparation and characterization of new NCN-pincer Co(III) complexes containing bis(oxazolinyl)phenyl (phebox) ligands as auxiliary ligands. The reaction of Co-2(CO)(8) with the 2-bromo-substituted ligand precursor (phebox-R)Br (1a, R = Me-2; 1b, R = iPr) resulted in the formation of the tricarbonyl Co(I) complex (phebox-R)Co(CO)(3) (2a, R = Me-2; 2b, R = iPr), in which NC-bidentate coordination of the phebox ligand was observed. Complexes 2 underwent oxidative addition of I-2 to give the Co(III) aqua complex (phebox-R)CoI2(H2O) (4a, R = Me-2; 4b, R = iPr) by a change in the coordination geometry to the NCN-tridentate mode. Ligand exchange reactions of H2O or I ligand with CNtBu or AgOAc smoothly proceeded to give the isocyanide complex (phebox-dm)CoI2(CNtBu) (5) or the acetate complex (phebox-dm)Co(kappa(1)-OAc)(kappa(2)-OAc) (6), respectively.
引用
收藏
页码：3980 / 3985
页数：6
相关论文
共 50 条
  • [41] Indolyl-based NCN-pincer titanium group metal complexes: Synthesis and catalytic application for styrene polymerization
    Liu Huanhuan
    Tong Yao
    Huang Jiangsheng
    Wang Fenhua
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2024, 40 (07) : 1261 - 1269
  • [42] Chiral NCN Pincer Iridium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Application in Enantioselective C-H Functionalization of Indoles with α-Aryl-α-diazoacetates
    Li, Nan
    Zhu, Wen-Jing
    Huang, Juan-Juan
    Hao, Xin-Qi
    Gong, Jun-Fang
    Song, Mao-Ping
    ORGANOMETALLICS, 2020, 39 (12) : 2222 - 2234
  • [43] Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multipotent Catalysts
    Ito, Jun-ichi
    Nishiyama, Hisao
    ORGANOMETALLIC PINCER CHEMISTRY, 2013, 40 : 243 - +
  • [44] Chiral nickel(II) and palladium(II) NCN-pincer complexes based on substituted benzene: Synthesis, structure, and lewis acidity
    Bugarin, Alejandro
    Connell, Brian T.
    ORGANOMETALLICS, 2008, 27 (17) : 4357 - 4369
  • [45] Cationic iron and cobalt complexes containing bis(imino)pyridyl ligands
    Gibson, Vernon C.
    Britovsek, George J. P.
    Spitzmesser, Stefan K.
    2000, ACS, Washington, DC, United States (41):
  • [46] Diastereopure cationic NCN-pincer palladium complexes with square planar η4-N,C,N,O coordination
    Gosiewska, Silvia
    Martinez, Sara Herreras
    Lutz, Martin
    Spek, Anthony L.
    van Koten, Gerard
    Gebbink, Robertus J. M. Klein
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (22) : 4600 - 4607
  • [47] Pincer Chromium(II) and Chromium(III) Complexes Supported by Bis(imino)aryl NCN ligands: Synthesis and Catalysis on Isoprene Polymerization
    Liu, Zhizhou
    Gao, Wei
    Liu, Xiaoming
    Luo, Xuyang
    Cui, Dongmei
    Mu, Ying
    ORGANOMETALLICS, 2011, 30 (04) : 749 - 756
  • [48] Synthesis and Structural Characterization of the First Copper(I) Complexes with Bis(imino)-N-heterocyclic Carbene NCN Pincer Ligands
    Al Thagfi, Jameel
    Dastgir, Sarim
    Lough, Alan J.
    Lavoie, Gino G.
    ORGANOMETALLICS, 2010, 29 (14) : 3133 - 3138
  • [49] Synthetic Utility of Chiral Bis(oxazolinyl)phenyl Transition-Metal Complexes
    Ito, Jun-ichi
    Nishiyama, Hisao
    SYNLETT, 2012, (04) : 509 - 523
  • [50] Rare-earth metal complexes supported by indolyl-based NCN-pincer ligand and their efficient catalysis for isoprene polymerization
    Chu, Cheng-Hao
    Wang, Xiang-Rui
    Huang, Jiang-Sheng
    Huang, Ze-Ming
    Li, Qing-Hai
    Wang, Fen -Hua
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1285
12345