NCN-Pincer Cobalt Complexes Containing Bis(oxazolinyl)phenyl Ligands

被引：12

作者：

Hosokawa, Satomi ^{[1
]}

Ito, Jun-ichi ^{[1
]}

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

ORGANOMETALLICS | 2013年 / 32卷 / 14期

基金：

日本学术振兴会;

关键词：

H BOND ACTIVATION; REGIOSPECIFIC CYCLOMETALATION; STRUCTURAL-CHARACTERIZATION; COORDINATION; ALDEHYDES; ARENES;

D O I：

10.1021/om400450n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We describe the preparation and characterization of new NCN-pincer Co(III) complexes containing bis(oxazolinyl)phenyl (phebox) ligands as auxiliary ligands. The reaction of Co-2(CO)(8) with the 2-bromo-substituted ligand precursor (phebox-R)Br (1a, R = Me-2; 1b, R = iPr) resulted in the formation of the tricarbonyl Co(I) complex (phebox-R)Co(CO)(3) (2a, R = Me-2; 2b, R = iPr), in which NC-bidentate coordination of the phebox ligand was observed. Complexes 2 underwent oxidative addition of I-2 to give the Co(III) aqua complex (phebox-R)CoI2(H2O) (4a, R = Me-2; 4b, R = iPr) by a change in the coordination geometry to the NCN-tridentate mode. Ligand exchange reactions of H2O or I ligand with CNtBu or AgOAc smoothly proceeded to give the isocyanide complex (phebox-dm)CoI2(CNtBu) (5) or the acetate complex (phebox-dm)Co(kappa(1)-OAc)(kappa(2)-OAc) (6), respectively.

引用

页码：3980 / 3985

页数：6

共 50 条

[21] NCN-Pincer Metal Complexes (Ti, Cr, V, Zr, Hf, and Nb) of the Phebox Ligand (S,S)-2,6-Bis(4′-isopropyl-2′-oxazolinyl)phenyl (vol 30, pg 2819, 2011)
Chuchuryukin, Alexey V.
Huang, Rubin
Lutz, Martin
Chadwick, John C.
van Faassen, Ernst E.
Spek, Anthony L.
van Koten, Gerard
ORGANOMETALLICS, 2011, 30 (24) : 6782 - 6782
[22] Platinum NCN-pincer complexes as catalysts for carbon-carbon bond formation.
Fossey, JS
Richards, CJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U184 - U184
[23] Synthesis and crystal structures of the first C2-symmetric bis-aldimine NCN-pincer complexes of platinum and palladium
Fossey, John S.
Russell, Mark L.
Malik, K. M. Abdul
Richards, Christopher J.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (22) : 4843 - 4848
[24] Synthesis and characterization of bioorganometallic conjugates composed of NCN-pincer platinum(II) complexes and uracil derivatives
Moriuchi, Toshiyuki
Noguchi, Shunichi
Sakamoto, Yuki
Hirao, Toshikazu
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (05) : 1089 - 1095
[25] The striking influence of solubility on the nuclearity of cobalt NCN pincer complexes
Kaefer, Matthias G.
Pecak, Jan
Stoeger, Berthold
Kirchner, Karl
MONATSHEFTE FUR CHEMIE, 2024, 155 (10): : 947 - 952
[26] Synthesis and supramolecular association of immobilized NCN-pincer platinum(II) complexes on hyperbranched polyglycerol supports
Stiriba, SE
Slagt, MQ
Kautz, H
Gebbink, RJMK
Thomann, R
Frey, H
van Koten, G
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) : 1267 - 1273
[27] para-functionalized NCN-pincer palladium(II) complexes:: Synthesis, catalysis and DFT calculations
Dijkstra, HP
Slagt, MQ
McDonald, A
Kruithof, CA
Kreiter, R
Mills, AM
Lutz, M
Spek, AL
Klopper, W
van Klink, GPM
van Koten, G
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (05) : 830 - 838
[28] Chiral bis(oxazolinyl)phenyl rhodium and palladium complexes
Motoyama, Y
Makihara, N
Mikami, Y
Aoki, K
Nishiyama, H
CHEMISTRY LETTERS, 1997, (09) : 951 - 952
[29] Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties
Batema, Guido D.
van Walree, Cornelis A.
van Klink, Gerard P. M.
Donega, Celso de Mello
Meijerink, Andries
Perez-Moreno, Javier
Clays, Koen
van Koten, Gerard
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 246 - 252
[30] Direct Conjugate Addition of Alkynes with α,β-Unsaturated Carbonyl Compounds Catalyzed by NCN-Pincer Ru Complexes
Ito, Jun-ichi
Fujii, Kohei
Nishiyama, Hisao
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (02) : 600 - 604

← 1 2 3 4 5 →