Cluster model for the catalytic hydrogenation of CFCs and the synthesis and structural characterisation (when X=Br) of [Pd-4(mu(3)-CF)(mu-X)(3)(PBu(3)(t))(4)] (X=Cl,Br)

被引：6

作者：

Vilar, R ^{[1
]}

Lawrence, SE ^{[1
]}

Mingos, DMP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 03期

关键词：

D O I：

10.1039/a607048e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses, characterisation and crystal structure (when X=Br) of [Pd-4(mu(3)-CF)(mu-X)(3)(PBu(3)(t))(4)] (X=Cl, Br) are reported; the mu(3)-CF moiety is hydrogenated to CFH3 under mild conditions and serves as a model for the heterogeneous hydrogenation of CFCs to HCFCs.

引用

页码：285 / 286

页数：2

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