Cluster model for the catalytic hydrogenation of CFCs and the synthesis and structural characterisation (when X=Br) of [Pd-4(mu(3)-CF)(mu-X)(3)(PBu(3)(t))(4)] (X=Cl,Br)

被引：6

作者：

Vilar, R ^{[1
]}

Lawrence, SE ^{[1
]}

Mingos, DMP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 03期

关键词：

D O I：

10.1039/a607048e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses, characterisation and crystal structure (when X=Br) of [Pd-4(mu(3)-CF)(mu-X)(3)(PBu(3)(t))(4)] (X=Cl, Br) are reported; the mu(3)-CF moiety is hydrogenated to CFH3 under mild conditions and serves as a model for the heterogeneous hydrogenation of CFCs to HCFCs.

引用

页码：285 / 286

页数：2

共 50 条

[11] NEW METHODS OF THE SYNTHESIS OF TRINUCLEAR CLUSTER MO3S7X4(X=CL,X=BR) MOLYBDENUM THIOHALIDES
FEDOROV, VE
MIRONOV, YV
KUZMINA, OA
FEDIN, VP
ZHURNAL NEORGANICHESKOI KHIMII, 1986, 31 (10): : 2476 - 2479
[12] Synthesis and structural characterisation of [Pd-2(mu-Br)(2)(PBu(t)(3))(2)], an example of a palladium(I)-palladium(I) dimer
Vilar, R
Mingos, DMP
Cardin, CJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (23): : 4313 - 4314
[13] Thermal behavior and decomposition kinetics of metallic cluster [(n-Bu)4N]3[WS4Ag3X3Br](X = Cl, Br, I)
Lu, ZR
Ding, YC
Xu, Y
Liu, Q
Lang, JP
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (11) : 1107 - 1111
[14] PREPARATION OF DIMOLYBDENUM CATIONS WITH TRIPLY BRIDGED CORES [MO2(MU-F)2(MU-X)(CO)4(PPH3)4]+ (X=F, CL, BR, OH), [MO2(MU-BR)N(MU-OH)3-N(CO)4(PPH3)4]+ (N=1, 2) AND DITUNGSTEN CATIONS [W(MU-F)N(MU-BR)3-N(CO)4(PPH3)4]+ CRYSTAL-STRUCTURE OF [MO2(MU-BR)(MU-F)2(CO)4(PPH3)4]F
FORD, A
SINN, E
WOODWARD, S
POLYHEDRON, 1994, 13 (04) : 635 - 645
[15] New polynuclear indium nitrogen compounds -: Synthesis and crystal structures of [In4X4(NtBu)4] (X = Cl, Br, I) and [In3Br4(NtBu)(NHtBu)3]
Grabowy, T
Merzweiler, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (03): : 736 - 740
[16] SYNTHESIS OF EDGE DOUBLE-BRIDGED RU3(MU-H,MU-X)(CO)10, X=O=C(ME), CL, BR, I, AND OF RU3(MU-H,MU-3-I)(CO)9 - A NEW SERIES OF REACTIVE COMPLEXES FOR TRIRUTHENIUM CLUSTER CHEMISTRY - CRYSTAL AND MOLECULAR-STRUCTURE OF RU3(MU-H,MU-BR)(CO)1
BOAG, NM
KAMPE, CE
LIN, YC
KAESZ, HD
INORGANIC CHEMISTRY, 1982, 21 (04) : 1706 - 1708
[17] THE GADOLINIUM CARBIDE HALIDES, GD(4)C(2)X(3) (X=CL,BR)
BAUHOFER, C
MATTAUSCH, H
KREMER, RK
SIMON, A
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (09): : 1501 - 1507
[18] OXIDATIVE ADDITION-REACTIONS TO (C5H4CH3)CO(CO)2 AND PREPARATION OF THE MONO-MU-HYDRIDO COMPLEXES [(C5H4CH3)COX]2(MU-H)(MU-X) (X=CL,BR,I)
DELGADO, S
MACAZAGA, J
MORENO, C
MASAGUER, JR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 289 (2-3) : 397 - 402
[19] OXIDATIVE OPENING OF METAL-METAL BONDS IN IRON-SULFUR-CARBONYL CLUSTERS - SYNTHESIS (X = CL, BR, I) AND STRUCTURE (X = CL) OF FE3(CO)9(MU-2-X)(MU-3-S-T-C4H9)
WINTER, A
ZSOLNAI, L
HUTTNER, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 232 (01) : 47 - 57
[20] SYNTHESIS AND PROPERTIES OF TETRAHYDROFURAN COMPLEXES OF CHROMIUM(III) - [CR(THF)3X3] (X = CL, BR, I), [CR(THF)2X4]- (X = CL, BR, I, NCS), AND [CR(THF)6](BF4)3
JONES, PJ
HALE, AL
LEVASON, W
MCCULLOUGH, FP
INORGANIC CHEMISTRY, 1983, 22 (18) : 2642 - 2644

← 1 2 3 4 5 →