Flame retardant epoxy resin based on bisphenol A epoxy resin modified by phosphoric acid

被引：38
|
作者：
Jiao, Chuanmei [1 ]
Zhuo, Jinlong [1 ]
Chen, Xilei [1 ]
Li, Shaoxiang [1 ]
Wang, Huajin [2 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Shandong, Peoples R China
[2] Marine Chem Res Inst, Qingdao 266071, Shandong, Peoples R China
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 114卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Epoxy resin; Flame retardant; Phosphoric acid; HYPERBRANCHED POLYPHOSPHATE ESTER; THERMAL-DECOMPOSITION; FLAMMABILITY; DEGRADATION; SYSTEMS;
D O I：
10.1007/s10973-012-2867-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Flame retardant epoxy resin (FREP) were synthesized from phosphoric acid and bisphenol A epoxy resin (BAEP). The structure of the FREP was characterized using FTIR and P-31 NMR. Then, several FREP/BAEP mass ratios were used to obtain materials with different phosphorus contents. The properties of the thermosetting materials were evaluated by limiting oxygen index, UL 94, cone calorimeter test, and thermogravimetric analysis. The results showed that the heat release rates and smoke production rates decreased greatly, and char residue increased with the increasing of FREP. It indicates that good flame retardant properties are related to the formation of a protective phosphorus-rich char layer.
引用
收藏
页码：253 / 259
页数：7
相关论文
共 50 条
  • [31] Synthesis and characterization of an novel flame retardant based on phosphaphenanthrene for epoxy resin
    Min, Yang
    Li, Pei
    Yin, Xiao-gang
    Ban, Da-ming
    POLYMER BULLETIN, 2017, 74 (01) : 1 - 10
  • [32] An Effective Method for Preparation of Liquid Phosphoric Anhydride and Its Application in Flame Retardant Epoxy Resin
    Li, Qian
    Li, Yujie
    Chen, Yifan
    Wu, Qiang
    Wang, Siqun
    MATERIALS, 2021, 14 (09)
  • [33] Nickel conductive adhesive based on bisphenol A epoxy resin modified by CTBN/dicyclopentadiene epoxy resin: Effects of epoxy resin structure on mechanical properties and thermal stability
    Xiong, Zikai
    Yu, Chunxiu
    Jing, Danlei
    Li, Yanhua
    Wang, Yunkai
    Hu, Yongqing
    Guo, Junmei
    Li, Wei
    Li, Junpeng
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1325
  • [34] Synthesis of the effective flame retardant via modification of epoxy resin with phenylboronic acid
    Abniki, Milad
    Hadavand, Behzad Shirkavand
    Najafi, Farhood
    Ghasedi, Iman
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2022, 59 (06): : 411 - 420
  • [35] Preparation and flame retardancy of intumescent flame-retardant epoxy resin
    Lu, L. (llg@iccas.ac.cn), 1600, Chinese Journal of Materials Research (28):
  • [36] Flame-Retardant Electrical Conductive Nanopolymers Based on Bisphenol F Epoxy Resin Reinforced with Nano Polyanilines
    Zhang, Xi
    He, Qingliang
    Gu, Hongbo
    Colorado, Henry A.
    Wei, Suying
    Guo, Zhanhu
    ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (03) : 898 - 910
  • [37] Synthesis of novel calixarene-based intumescent flame retardant and application of flame retardant epoxy resin
    Zhang, Dingran
    Lu, Lingang
    Chen, Lei
    Wang, Yiqi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2022, 139 (16)
  • [38] Bisphenol-A epoxy resin reinforced and toughened by hyperbranched epoxy resin
    Daohong Zhang
    Demin Jia
    Xianbo Huang
    Frontiers of Chemical Engineering in China, 2007, 1 (4): : 349 - 354
  • [39] Synergistic Flame Retardant Effect of Barium Phytate and Intumescent Flame Retardant for Epoxy Resin
    Wang, Linyuan
    Wei, Yue
    Deng, Hongbo
    Lyu, Ruiqi
    Zhu, Jiajie
    Yang, Yabing
    POLYMERS, 2021, 13 (17)
  • [40] Thermal stability and flame retardancy of an epoxy resin modified with phosphoric triamide and glycidyl POSS
    Li, Jialiang
    Wang, Hongyu
    Li, Shichao
    HIGH PERFORMANCE POLYMERS, 2019, 31 (9-10) : 1217 - 1225
12345