Flame retardant epoxy resin based on bisphenol A epoxy resin modified by phosphoric acid

被引：38
|
作者：
Jiao, Chuanmei [1 ]
Zhuo, Jinlong [1 ]
Chen, Xilei [1 ]
Li, Shaoxiang [1 ]
Wang, Huajin [2 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Shandong, Peoples R China
[2] Marine Chem Res Inst, Qingdao 266071, Shandong, Peoples R China
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 114卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Epoxy resin; Flame retardant; Phosphoric acid; HYPERBRANCHED POLYPHOSPHATE ESTER; THERMAL-DECOMPOSITION; FLAMMABILITY; DEGRADATION; SYSTEMS;
D O I：
10.1007/s10973-012-2867-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Flame retardant epoxy resin (FREP) were synthesized from phosphoric acid and bisphenol A epoxy resin (BAEP). The structure of the FREP was characterized using FTIR and P-31 NMR. Then, several FREP/BAEP mass ratios were used to obtain materials with different phosphorus contents. The properties of the thermosetting materials were evaluated by limiting oxygen index, UL 94, cone calorimeter test, and thermogravimetric analysis. The results showed that the heat release rates and smoke production rates decreased greatly, and char residue increased with the increasing of FREP. It indicates that good flame retardant properties are related to the formation of a protective phosphorus-rich char layer.
引用
收藏
页码：253 / 259
页数：7
相关论文
共 50 条
  • [21] Properties of DOPS/TPT Flame Retardant Epoxy Resin
    Xu S.
    Qi Y.
    Xu Q.
    Huan X.
    Bao D.
    Zhang D.
    Qin S.
    Xiang Y.
    Zhang Y.
    Tan F.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2024, 40 (03): : 66 - 75
  • [22] Numerical simulation of combustion of flame retardant epoxy resin
    Shan X.
    Zhang M.
    Zhang J.
    Li L.
    Song Y.
    Li J.
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2023, 42 (07): : 3413 - 3419
  • [23] Flame retardant epoxy resin containing magnesium phosphinate
    Chen, Jia
    Liu, Jiyan
    Liu, Xueqing
    Sun, Shan
    ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5, 2013, 634-638 : 1927 - 1930
  • [24] Synthesis of a new flame retardant and performance study of flame retardant epoxy resin
    Meng, Bowei
    Song, Miaohui
    Liang, Bing
    Long, Jiapeng
    HIGH PERFORMANCE POLYMERS, 2025, 37 (01) : 32 - 39
  • [25] Synergistic Flame Retardant of Epoxy Resin Composites Based on Solid Super Acid and Montmorillonite Modified Ammonium Polyphosphate
    Chen X.
    Wan M.
    Zhou X.
    Gao M.
    Yi D.
    Wang Y.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2021, 37 (04): : 49 - 55and62
  • [26] Study on Methyl Substitued Diarylphosphine Oxide Flame Retardant Modified Epoxy Resin
    Wu, Mei
    Xu, Xiaolei
    Li, Xiao
    Liu, Jiuhong
    Yu, Guangrui
    Duan, Haodong
    Han, Yuxi
    Yu, Qing
    Wang, Zhongwei
    Cailiao Daobao/Materials Reports, 2024, 38 (16):
  • [27] Study on Anti-ultraviolet Aging of Flame Retardant Modified Epoxy Resin
    Zhao M.
    Wang J.
    Ni A.
    Chen J.
    Wang C.
    Wu Z.
    Cailiao Daobao/Materials Reports, 2024, 38 (01):
  • [28] Flame retardant epoxy resin composites modified with organophosphorus and boron hybrid molecules
    Ji R.
    Chen T.
    Peng C.
    Xia L.
    Chen G.
    Luo W.
    Zeng B.
    Xu Y.
    Yuan C.
    Dai L.
    Huagong Xuebao/CIESC Journal, 2021, 72 (07): : 3856 - 3868
  • [29] Synthesis and characterization of an novel flame retardant based on phosphaphenanthrene for epoxy resin
    Yang Min
    Pei Li
    Xiao-gang Yin
    Da-ming Ban
    Polymer Bulletin, 2017, 74 : 1 - 10
  • [30] Preparation of a novel lignin-based flame retardant for epoxy resin
    Liang, Dingxiang
    Zhu, Xiaojun
    Dai, Peng
    Lu, Xinyu
    Guo, Haoquan
    Que, Han
    Wang, Dandan
    He, Tao
    Xu, Chaozhong
    Robin, Hossain Mahmud
    Luo, Zhenyang
    Gu, Xiaoli
    MATERIALS CHEMISTRY AND PHYSICS, 2021, 259
12345