Recent Progress in the C-N Bond Formation via High-Valent Group 9 Cp*M(III)-Catalyzed Directed sp2C-H Activation

被引：34

作者：

Sk, Md Raja ^{[1
]}

Bera, Sourav Sekhar ^{[1
]}

Basuli, Suchand ^{[1
]}

Metya, Abhisek ^{[1
]}

Maji, Modhu Sudan ^{[1
]}

机构：

[1] Indian Inst Technol Kharagpur, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 9卷 / 11期

关键词：

C-H activation; C-N bond formation; cobalt(III); rhodium(III); iridium(III); SITE-SELECTIVE AMIDATION; H AMIDATION; ORTHO-C(SP(2))-H AMIDATION; AMINATION; ARENES; ALDEHYDES; INDOLES; AZIDES; MILD; 2-AMINOBENZALDEHYDES;

D O I：

10.1002/ajoc.202000367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The presence of nitrogen atom in a wide variety of organic compounds called for the use of powerful C-H activation strategy in the C-N bond formation. Pentamethylcyclopentadienyl (Cp*) based, high-valent, group 9 transition-metal complexes have shown a great potential as catalysts in the C-H activation/functionalization over the years. This minireview summarizes recent progress made in the context of C-N bond formation via catalytic (sp(2))C-H activation with Cp*M(III) (M=Co, Rh and Ir) catalysts. A general plausible mechanism is briefly discussed at the beginning, and then results are arranged according to metal cobalt, rhodium and iridium, respectively.

引用

页码：1701 / 1717

页数：17

共 50 条

[41] Cobalt-Catalyzed C(sp2)-O Bond Formation by Directing Group Assisted C-H Activation
Park, Jinhwan
Son, Jongwoo
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 2022 (39)
[42] Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C-H Activation and C-C/C-N Bond Cleavage
Qi, Zisong
Yu, Songjie
Li, Xingwei
ORGANIC LETTERS, 2016, 18 (04) : 700 - 703
[43] Synchronous double C-N bond formation via C-H activation for a novel synthetic route to phenazine
Seth, Kapileswar
Roy, Sudipta Raha
Chakraborti, Asit K.
CHEMICAL COMMUNICATIONS, 2016, 52 (05) : 922 - 925
[44] Ruthenium(II)-catalyzed C-H activation/C-N bond formation via in situ generated iminophosphorane as the directing group: construction of annulated pyridin-2(1H)-ones
Arigela, Rajesh K.
Kumar, Ravi
Joshi, Trapti
Mahar, Rohit
Kundu, Bijoy
RSC ADVANCES, 2014, 4 (101) : 57749 - 57753
[45] Palladium(ii)-catalyzed oxidative C(sp3)-P bond formation via C(sp3)-H bond activation
Chen, Lijin
Zhou, Zhenfei
Zhang, Saifei
Li, Xiaoqian
Ma, Xuebing
Dong, Jiaxing
CHEMICAL COMMUNICATIONS, 2019, 55 (91) : 13693 - 13696
[46] Recent advances in intramolecular C-O/C-N/C-S bond formation via C-H functionalization
Borpatra, Paran J.
Deka, Bhaskar
Deb, Mohit L.
Baruah, Pranjal K.
ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (20) : 3445 - 3489
[47] Selective C(sp2)-H Amination Catalyzed by High-Valent Cobalt(III)/(IV)-bpy Complex Immobilized on Silica Nanoparticles
Budnikova, Yulia
Bochkova, Olga
Khrizanforov, Mikhail
Nizameev, Irek
Kholin, Kirill
Gryaznova, Tatyana
Laskin, Artem
Dudkina, Yulia
Strekalova, Sofia
Fedorenko, Svetlana
Kononov, Aleksandr
Mustafina, Asia
CHEMCATCHEM, 2019, 11 (22) : 5615 - 5624
[48] Palladium Catalyzed C-C and C-N Bond Formation via ortho C-H Activation and Decarboxylative Strategy: A Practical Approach towards N-Acylated Indoles
Kumar, Saurabh
Singh, Rahul
Singh, Krishna Nand
ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (03) : 422 - 426
[49] Microwave-Assisted Cp*CoIII-Catalyzed C-H Activation/Double C-N Bond Formation Reactions to Thiadiazine 1-Oxides
Huang, Jiapian
Huang, Yangfei
Wang, Tao
Huang, Qin
Wang, Zhihua
Chen, Zhiyuan
ORGANIC LETTERS, 2017, 19 (05) : 1128 - 1131
[50] Palladium-Catalyzed sp2 C-N Bond Forming Reactions: Recent Developments and Applications
Lemen, Georgia S.
Wolfe, John P.
AMINATION AND FORMATION OF SP2 C-N BONDS, 2013, 46 : 1 - 53

← 1 2 3 4 5 →