Recent Progress in the C-N Bond Formation via High-Valent Group 9 Cp*M(III)-Catalyzed Directed sp2C-H Activation

被引：34

作者：

Sk, Md Raja ^{[1
]}

Bera, Sourav Sekhar ^{[1
]}

Basuli, Suchand ^{[1
]}

Metya, Abhisek ^{[1
]}

Maji, Modhu Sudan ^{[1
]}

机构：

[1] Indian Inst Technol Kharagpur, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 9卷 / 11期

关键词：

C-H activation; C-N bond formation; cobalt(III); rhodium(III); iridium(III); SITE-SELECTIVE AMIDATION; H AMIDATION; ORTHO-C(SP(2))-H AMIDATION; AMINATION; ARENES; ALDEHYDES; INDOLES; AZIDES; MILD; 2-AMINOBENZALDEHYDES;

D O I：

10.1002/ajoc.202000367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The presence of nitrogen atom in a wide variety of organic compounds called for the use of powerful C-H activation strategy in the C-N bond formation. Pentamethylcyclopentadienyl (Cp*) based, high-valent, group 9 transition-metal complexes have shown a great potential as catalysts in the C-H activation/functionalization over the years. This minireview summarizes recent progress made in the context of C-N bond formation via catalytic (sp(2))C-H activation with Cp*M(III) (M=Co, Rh and Ir) catalysts. A general plausible mechanism is briefly discussed at the beginning, and then results are arranged according to metal cobalt, rhodium and iridium, respectively.

引用

页码：1701 / 1717

页数：17

共 50 条

[21] Electroactivated transition-metal catalyzed C-H activation to promote C-N bond formation
Bhatia, Souful
Jackson, James
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[22] Palladium(II)-Catalyzed C(sp2)-H Bond Activation/C-N Bond Cleavage Annulation of N-Methoxy Amides and Arynes
Cheng, Xiu-Fen
Yu, Ting
Liu, Yi
Wang, Nan
Chen, Zhenzhen
Zhang, Guang-Lu
Tong, Lili
Tang, Bo
ORGANIC LETTERS, 2022, 24 (11) : 2087 - 2092
[23] Pd-catalyzed imine-directed intramolecular C-N bond formation through C(sp3)-H activation: An efficient approach to multisubstituted pyrroles
Yu, Ting
Zhu, Qiang
Luo, Shuang
TETRAHEDRON LETTERS, 2020, 61 (21)
[24] Recent advances in nickel-catalyzed C-C and C-N bond formation via HA and ADC reactions
Subaramanian, Murugan
Sivakumar, Ganesan
Balaraman, Ekambaram
ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (19) : 4213 - 4227
[25] Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation
Colby, Denise A.
Bergman, Robert G.
Ellman, Jonathan A.
CHEMICAL REVIEWS, 2010, 110 (02) : 624 - 655
[26] Recent advances in Co-catalyzed C-C and C-N bond formation via ADC and ATH reactions
Zhang, Meng-Juan
Ge, Xiao-Lan
Young, David J.
Li, Hong-Xi
TETRAHEDRON, 2021, 93
[27] Palladium-Catalyzed C(sp2)-H Activation for the Formation of C-N Bonds: Rapid Access to Benzimidazoquinazolines
Guo, Xiaolong
Hu, Jing
Zhang, Mengmeng
Wang, Luyao
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (03) : 417 - 421
[28] C-C Bond Formation via C-H Activation and C-N Bond Formation via Oxidative Amination Catalyzed by Palladium-Polyoxometalate Nanomaterials Using Dioxygen as the Terminal Oxidant
Chng, Leng Leng
Zhang, Jie
Yang, Jinhua
Amoura, Makhlouf
Ying, Jackie Y.
ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (16) : 2988 - 2998
[29] Palladium-Catalyzed C-F Bond Formation via Directed C-H Activation
Li, Yan
Wu, Yun
Li, Guang-Shui
Wang, Xi-Sheng
ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (07) : 1412 - 1418
[30] Cul Controlled C-C and C-N Bond Formation of Heteroaromatics through C(sp3)-H Activation
Xia, Ran
Niu, Hong-Ying
Qu, Gui-Rong
Guo, Hai-Ming
ORGANIC LETTERS, 2012, 14 (21) : 5546 - 5549

← 1 2 3 4 5 →