Recent Progress in the C-N Bond Formation via High-Valent Group 9 Cp*M(III)-Catalyzed Directed sp2C-H Activation

被引：34

作者：

Sk, Md Raja ^{[1
]}

Bera, Sourav Sekhar ^{[1
]}

Basuli, Suchand ^{[1
]}

Metya, Abhisek ^{[1
]}

Maji, Modhu Sudan ^{[1
]}

机构：

[1] Indian Inst Technol Kharagpur, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 9卷 / 11期

关键词：

C-H activation; C-N bond formation; cobalt(III); rhodium(III); iridium(III); SITE-SELECTIVE AMIDATION; H AMIDATION; ORTHO-C(SP(2))-H AMIDATION; AMINATION; ARENES; ALDEHYDES; INDOLES; AZIDES; MILD; 2-AMINOBENZALDEHYDES;

D O I：

10.1002/ajoc.202000367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The presence of nitrogen atom in a wide variety of organic compounds called for the use of powerful C-H activation strategy in the C-N bond formation. Pentamethylcyclopentadienyl (Cp*) based, high-valent, group 9 transition-metal complexes have shown a great potential as catalysts in the C-H activation/functionalization over the years. This minireview summarizes recent progress made in the context of C-N bond formation via catalytic (sp(2))C-H activation with Cp*M(III) (M=Co, Rh and Ir) catalysts. A general plausible mechanism is briefly discussed at the beginning, and then results are arranged according to metal cobalt, rhodium and iridium, respectively.

引用

页码：1701 / 1717

页数：17

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