Concentration induced damping of gas sensitivity in ultrathin tellurium films

被引:16
|
作者
Tsiulyanu, D. [1 ]
Mocreac, O. [1 ]
机构
[1] Tech Univ, Dept Phys, MD-2060 Kishinev, Moldova
来源
关键词
Gas sensitivity; Damping; Tellurium; Ultrathin layers; NO2; SENSING PROPERTIES; THIN-FILMS; NO2;
D O I
10.1016/j.snb.2012.12.022
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The damping of sensitivity induced by high gas (NO2) concentration in tellurium films was observed for the first time. The phenomenon becomes apparent in ultrathin (less than 40 nm) shown by AFM, SEM and XRD analyses to be in amorphous state. Sensitivity of 30 nm thickness Te film decreases near linearly with concentration increase between 150 and 500 ppb of nitrogen dioxide. Results are explained in terms of formation of a nitrogen dioxide catalytic gate in which a molecule adsorbs (and desorbs) without reacting. (c) 2012 Published by Elsevier B.V.
引用
收藏
页码:1128 / 1133
页数:6
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