Tartaric Acid as a Complexing Agent for Selective Removal of Tantalum and Copper in CMP

被引:33
|
作者
Janjam, S. V. S. B. [1 ]
Peddeti, S. [1 ]
Roy, D. [2 ]
Babu, S. V. [1 ]
机构
[1] Clarkson Univ, Ctr Adv Mat Proc, Potsdam, NY 13699 USA
[2] Clarkson Univ, Dept Phys, Potsdam, NY 13699 USA
关键词
D O I
10.1149/1.2980345
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This work demonstrates the utility of a tartaric acid-based slurry for chemical mechanical planarization (CMP) of tantalum and copper. Cu and Ta disks and wafers were polished at a pressure of 2 psi, and selective removal of the two metals was achieved by adjusting the pH of the slurry in the range 3.0-8.0. Changing the H(2)O(2) content of the slurry can further regulate the relative removal rates of Cu and Ta. Optical profilometry shows very good postpolish wafer surface quality. Possible mechanisms for the chemically promoted material removal are discussed. (C) 2008 The Electrochemical Society. [DOI: 10.1149/1.2980345] All rights reserved.
引用
收藏
页码:H327 / H330
页数:4
相关论文
共 50 条
  • [21] Investigation of polyhydroxy polyamino complexing agent on CMP of TSV wafer
    Institute of Microelectronics, Hebei University of Technology, Tianjin 300130, China
    Gongneng Cailiao, 2013, 24 (3603-3605+3610):
  • [22] Selectivity studies on tantalum barrier layer in copper CMP
    Vijayakumar, A
    Du, TB
    Sundaram, KB
    Desai, V
    CHEMICAL-MECHANICAL PLANARIZATION, 2003, 767 : 251 - 256
  • [23] Hydrophobic tartaric acid monoamides as complexing and tensioactive agents
    Giroux, S
    Rubini, P
    Gérardin, C
    Selve, C
    Henry, B
    NEW JOURNAL OF CHEMISTRY, 2000, 24 (03) : 173 - 178
  • [24] Selective cloud point extraction and preconcentration of copper by the use of dithizone as a complexing agent
    Manzoori, JL
    Karim-Nezhad, G
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2005, 24 (04): : 47 - 52
  • [25] Antimony Sulfide Thin Films Obtained by Chemical Bath Deposition using Tartaric Acid as Complexing Agent
    Escorcia-Garcia, J.
    Dominguez-Diaz, M.
    Hernandez-Granados, A.
    Martinez, H.
    MRS ADVANCES, 2018, 3 (56): : 3307 - 3313
  • [26] Antimony Sulfide Thin Films Obtained by Chemical Bath Deposition using Tartaric Acid as Complexing Agent
    J. Escorcia-García
    M. Domínguez-Díaz
    A. Hernández-Granados
    H. Martínez
    MRS Advances, 2018, 3 (56) : 3307 - 3313
  • [27] Exploration of the copper CMP removal mechanism
    Advanced Products Research and, Development Lab , Austin, United States
    Materials Research Society Symposium - Proceedings, 2000, 566 : 155 - 160
  • [28] An exploration of the copper CMP removal mechanism
    Renteln, P
    Ninh, T
    CHEMICAL-MECHANICAL POLISHING - FUNDAMENTALS AND CHALLENGES, 2000, 566 : 155 - 160
  • [29] THE DETERMINATION OF TANTALUM BY THE REACTION WITH PYROGALLOL IN THE PRESENCE OF TARTARIC ACID
    DOBKINA, BM
    PETROVA, EI
    INDUSTRIAL LABORATORY, 1959, 25 (09): : 1107 - 1110
  • [30] The functional group effect of complexing agent on Cu CMP in the neutral environment
    Bae, JaeHan
    Kim, Yung Jun
    Kim, Jae Jeong
    PROCESSING, MATERIALS, AND INTEGRATION OF DAMASCENE AND 3D INTERCONNECTS, 2010, 25 (38): : 155 - 160