Synthesis and reactions of the first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues

被引:2
|
作者
Kishikawa, K [1 ]
Tokitoh, N [1 ]
Okazaki, R [1 ]
机构
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan
关键词
1-germaallene 1,2-chalcogenides; steric protection; germylene; 1-germaallene; X-ray analysis;
D O I
10.1080/10426509808042651
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues are synthesized by the addition of chalcogen source to the reaction mixture of germanium divalent species such as Tbt(Mes)Ge: (Tbt = 2,4,6-tris[bis(trimethylsilyl) methyl]-phenyl; Mes = mesityl) and alpha,alpha -dichloroalkene.
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页码:505 / 508
页数:4
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