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Synthesis and reactions of the first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues
被引:2
|作者:
Kishikawa, K
[1
]
Tokitoh, N
[1
]
Okazaki, R
[1
]
机构:
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan
关键词:
1-germaallene 1,2-chalcogenides;
steric protection;
germylene;
1-germaallene;
X-ray analysis;
D O I:
10.1080/10426509808042651
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues are synthesized by the addition of chalcogen source to the reaction mixture of germanium divalent species such as Tbt(Mes)Ge: (Tbt = 2,4,6-tris[bis(trimethylsilyl) methyl]-phenyl; Mes = mesityl) and alpha,alpha -dichloroalkene.
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页码:505 / 508
页数:4
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