Synthesis and reactions of the first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues

被引:2
|
作者
Kishikawa, K [1 ]
Tokitoh, N [1 ]
Okazaki, R [1 ]
机构
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan
关键词
1-germaallene 1,2-chalcogenides; steric protection; germylene; 1-germaallene; X-ray analysis;
D O I
10.1080/10426509808042651
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first stable 1-germaallene 1,2-telluride and its sulfur and selenium analogues are synthesized by the addition of chalcogen source to the reaction mixture of germanium divalent species such as Tbt(Mes)Ge: (Tbt = 2,4,6-tris[bis(trimethylsilyl) methyl]-phenyl; Mes = mesityl) and alpha,alpha -dichloroalkene.
引用
收藏
页码:505 / 508
页数:4
相关论文
共 50 条
  • [31] Cobalt-catalyzed carbon-sulfur/selenium bond formation: synthesis of benzo[b]thio/selenophene-fused imidazo[1,2-a]pyridines
    Wang, Tianyu
    Chen, Jichao
    Wang, Jia
    Xu, Shengtao
    Lin, Aijun
    Yao, Hequan
    Jiang, Sheng
    Xu, Jinyi
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (20) : 3721 - 3725
  • [32] Copper-Catalyzed One-Pot Synthesis of Chalcogen-Benzothiazoles/Imidazo[1,2-a]pyridines with Sulfur/Selenium Powder and Aryl Boronic Acids
    Guo, Tao
    Wei, Xu-Ning
    Zhu, Ying-Li
    Chen, Huan
    Han, Shu-Lei
    Ma, Yong-Cheng
    SYNLETT, 2018, 29 (11) : 1530 - 1536
  • [33] Facile synthesis of a 56π-electron 1,2-dihydromethano-[60]PCBM and its application for thermally stable polymer solar cells
    Li, Chang-Zhi
    Chien, Shang-Chieh
    Yip, Hin-Lap
    Chueh, Chu-Chen
    Chen, Fang-Chung
    Matsuo, Yutaka
    Nakamura, Eiichi
    Jen, Alex K. -Y.
    CHEMICAL COMMUNICATIONS, 2011, 47 (36) : 10082 - 10084
  • [34] Selenium-nitrogen bond formation by ring expansion: Synthesis of the 1,4,2-diselenazine ring system, fragmentation to a 1,2-diselenete and reactions to yield 1,4-diselenin derivatives
    Yoshida, S
    Bryce, MR
    Chesney, A
    CHEMICAL COMMUNICATIONS, 1996, (20) : 2375 - 2376
  • [35] Synthesis of pyrrolo[1,2-a]quinoxaline and its 4-(1-hydroxyalkyl) derivatives by Lewis acid-catalyzed reactions of 1-(2-isocyanophenyl)pyrrole
    Kobayashi, K
    Matoba, T
    Irisawa, S
    Matsumoto, T
    Morikawa, O
    Konishi, H
    CHEMISTRY LETTERS, 1998, (06) : 551 - 552
  • [36] Improved selectivity for Pb(II) by sulfur, selenium and tellurium analogues of 1,8-anthraquinone-18-crown-5: synthesis, spectroscopy, X-ray crystallography and computational studies
    Mariappan, Kadarkaraisamy
    Alaparthi, Madhubabu
    Hoffman, Mariah
    Rama, Myriam Alcantar
    Balasubramanian, Vinothini
    John, Danielle M.
    Sykes, Andrew G.
    DALTON TRANSACTIONS, 2015, 44 (26) : 11774 - 11787
  • [37] Polyunsaturated sulfur/selenium-containing products based on regio- and stereoselective nucleophilic addition and substitution reactions of 1,2-bis[(Z)-2-(vinylsulfanyl)ethenyl] diselane
    Amosova, Svetlana V. V.
    Filippov, Andrey S. S.
    Makhaeva, Nataliya A. A.
    Albanov, Alexander I. I.
    Potapov, Vladimir A. A.
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (24) : 11505 - 11514
  • [38] Synthesis of indole alkaloid analogues containing the novel hexahydropyrrolo[1′,2′,3′:1,9a,9]imidazo[1,2-a]indole skeleton by ring-closing reactions of tryptophan-derived α-amino nitriles
    Gonzalez-Vera, Juan A.
    Garcia-Lopez, M. Teresa
    Herranz, Rosario
    TETRAHEDRON, 2007, 63 (37) : 9229 - 9234
  • [39] Synthesis and biological evaluation of the new ring system benzo[f]pyrimido[1,2-d][1,2,3]triazolo[1,5-a][1,4]diazepine and its cycloalkane and cycloalkene condensed analogues
    El Haimer, Mohamed
    Palko, Marta
    Haukka, Matti
    Gajdacs, Mario
    Zupko, Istvan
    Fulop, Ferenc
    RSC ADVANCES, 2021, 11 (12) : 6952 - 6957
  • [40] 1,4-benzoxazino[2,3-b]phenoxazine and its sulfur analogues:: Synthesis, properties, and application to organic light-emitting diodes
    Okamoto, T
    Kozaki, M
    Doe, M
    Uchida, M
    Wang, GF
    Okada, K
    CHEMISTRY OF MATERIALS, 2005, 17 (22) : 5504 - 5511