Unusual crystal and molecular structure of tris(2-hydroxyethyl)ammonium fluoride

被引：10

作者：

Voronkov, M. G. ^{[1
,4
]}

Korlyukov, A. A. ^{[2
]}

Kochina, T. A. ^{[1
]}

Zel'bst, E. A. ^{[3
]}

机构：

[1] Russian Acad Sci, AV Grebenshchikov Inst Silicate Chem, St Petersburg, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 117901, Russia

[3] East Siberian State Acad Educ, Irkutsk, Russia

[4] Russian Acad Sci, AE Favorsky Inst Chem, Siberian Div, Irkutsk 664003, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 01期

关键词：

tris(2-hydroxyethyl)ammonium halides; protatranes; molecular structure; single crystal X-ray diffraction study;

D O I：

10.1134/S0022476613010319

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

According to the X-ray diffraction data, the crystal and molecular structure of tris(2-hydroxyethyl) ammonium fluoride (F-N+H(CH2CH2OH)(3), fluoroprotatrane, substantially differs from other halo protatranes X-N+H(CH2CH2OH)(3) (X = Cl, Br, and I). At X = F, to the endo-molecular LP of the nitrogen atom the HF molecule having the minimum ionic radius in a series of X- anions is bonded. The geometry of fluoroprotatrane and the cation packing in the crystal are analyzed.

引用

页码：192 / 195

页数：4

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