Unusual crystal and molecular structure of tris(2-hydroxyethyl)ammonium fluoride

被引：10
|
作者：
Voronkov, M. G. [1 ,4 ]
Korlyukov, A. A. [2 ]
Kochina, T. A. [1 ]
Zel'bst, E. A. [3 ]
机构：
[1] Russian Acad Sci, AV Grebenshchikov Inst Silicate Chem, St Petersburg, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 117901, Russia
[3] East Siberian State Acad Educ, Irkutsk, Russia
[4] Russian Acad Sci, AE Favorsky Inst Chem, Siberian Div, Irkutsk 664003, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 01期
关键词：
tris(2-hydroxyethyl)ammonium halides; protatranes; molecular structure; single crystal X-ray diffraction study;
D O I：
10.1134/S0022476613010319
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
According to the X-ray diffraction data, the crystal and molecular structure of tris(2-hydroxyethyl) ammonium fluoride (F-N+H(CH2CH2OH)(3), fluoroprotatrane, substantially differs from other halo protatranes X-N+H(CH2CH2OH)(3) (X = Cl, Br, and I). At X = F, to the endo-molecular LP of the nitrogen atom the HF molecule having the minimum ionic radius in a series of X- anions is bonded. The geometry of fluoroprotatrane and the cation packing in the crystal are analyzed.
引用
收藏
页码：192 / 195
页数：4
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