Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

被引：4

作者：

Takamura, Hiroyoshi ^{[1
]}

Fujiwara, Takayuki ^{[1
]}

Kadota, Isao ^{[1
]}

Uemura, Daisuke ^{[2
]}

机构：

[1] Okayama Univ, Dept Chem, Grad Sch Nat Sci & Technol, Kita Ku, Okayama 7008530, Japan

[2] Kanagawa Univ, Dept Chem, Fac Sci, Hiratsuka, Kanagawa 2591293, Japan

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷

基金：

日本学术振兴会;

关键词：

Julia-Kocienski olefination; polyol marine natural product; Sharpless asymmetric dihydroxylation; spiroacetalization; symbiodinolide; ABSOLUTE-CONFIGURATION; STEREOCONTROLLED SYNTHESIS; C33-C42; FRAGMENT; CONDENSATION; OXIDATION; ALDEHYDES;

D O I：

10.3762/bjoc.9.228

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.

引用

页码：1931 / 1935

页数：5

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