Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes

被引：10
|
作者：
Kulik, AV [1 ]
Bruk, LG
Temkin, ON
Khabibulin, VR
Belsky, VK
Zavodnik, VE
机构：
[1] MV Lomonosov State Acad Fine Chem Technol, Moscow 117571, Russia
[2] LY Karpov Phys Chem Res Inst, Moscow 103064, Russia
来源：
MENDELEEV COMMUNICATIONS | 2002年 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1070/MC2002v012n02ABEH001577
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complexes [Pd(eta(2)-Q)(PPh3)(2)](2)H(2)Q and Pd-2(mu-eta(2),eta(2)-Q)(2)(PPh3)(2) (where Q and H(2)Q are p-benzoquinone and hydroquinone, respectively) were synthesised and structurally characterised, and their catalytic activity in the oxidative carbonylation of phenylacetylene to methyl phenylpropiolate was examined.
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页码：47 / 48
页数：2
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