Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes

被引：10

作者：

Kulik, AV ^{[1
]}

Bruk, LG

Temkin, ON

Khabibulin, VR

Belsky, VK

Zavodnik, VE

机构：

[1] MV Lomonosov State Acad Fine Chem Technol, Moscow 117571, Russia

[2] LY Karpov Phys Chem Res Inst, Moscow 103064, Russia

来源：

MENDELEEV COMMUNICATIONS | 2002年 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2002v012n02ABEH001577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [Pd(eta(2)-Q)(PPh3)(2)](2)H(2)Q and Pd-2(mu-eta(2),eta(2)-Q)(2)(PPh3)(2) (where Q and H(2)Q are p-benzoquinone and hydroquinone, respectively) were synthesised and structurally characterised, and their catalytic activity in the oxidative carbonylation of phenylacetylene to methyl phenylpropiolate was examined.

引用

页码：47 / 48

页数：2

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