Effect of reactant gas flow orientation on the current and temperature distribution in self-heating polymer electrolyte fuel cells

被引:13
|
作者
Rasha, L. [1 ]
Cho, J. I. S. [1 ]
Millichamp, J. [1 ]
Neville, T. P. [1 ]
Shearing, P. R. [1 ]
Brett, D. J. L. [1 ]
机构
[1] UCL, Electrochem Innovat Lab, Dept Chem Engn, London WC1E 7JE, England
基金
英国工程与自然科学研究理事会;
关键词
Self-heating; Non-isothermal; Voltage recovery; Current distribution mapping; Temperature distribution mapping; Flow orientation;
D O I
10.1016/j.ijhydene.2020.11.223
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cell polarisation performance is typically reported under controlled/constant temperature conditions, as a sign of robust metrology. However, in practice, fuel cells self-heat as they generate current; which varies the temperature across the polarisation curve and affects performance. More detail regarding the internal cell operation can be gleaned by current and temperature distribution mapping. For the case of an unheated cell, 'self-heating' increases the cell temperature and improves performance, resulting in a 'voltage recovery' and a more homogeneous current and water distribution. For actively heated cells, a reduced current is observed in regions of high temperature and low humidity. The positioning of the gas manifolds also has a decisive impact on performance by affecting the reactant concentration, humidity and water distribution. Counter- and cross-flow orientations in a self-heating cell were studied, with a counter-flow orientation with air flowing with gravity producing the most uniform temperature distribution. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7502 / 7514
页数:13
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