Effect of reactant gas flow orientation on the current and temperature distribution in self-heating polymer electrolyte fuel cells

被引:13
|
作者
Rasha, L. [1 ]
Cho, J. I. S. [1 ]
Millichamp, J. [1 ]
Neville, T. P. [1 ]
Shearing, P. R. [1 ]
Brett, D. J. L. [1 ]
机构
[1] UCL, Electrochem Innovat Lab, Dept Chem Engn, London WC1E 7JE, England
基金
英国工程与自然科学研究理事会;
关键词
Self-heating; Non-isothermal; Voltage recovery; Current distribution mapping; Temperature distribution mapping; Flow orientation;
D O I
10.1016/j.ijhydene.2020.11.223
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cell polarisation performance is typically reported under controlled/constant temperature conditions, as a sign of robust metrology. However, in practice, fuel cells self-heat as they generate current; which varies the temperature across the polarisation curve and affects performance. More detail regarding the internal cell operation can be gleaned by current and temperature distribution mapping. For the case of an unheated cell, 'self-heating' increases the cell temperature and improves performance, resulting in a 'voltage recovery' and a more homogeneous current and water distribution. For actively heated cells, a reduced current is observed in regions of high temperature and low humidity. The positioning of the gas manifolds also has a decisive impact on performance by affecting the reactant concentration, humidity and water distribution. Counter- and cross-flow orientations in a self-heating cell were studied, with a counter-flow orientation with air flowing with gravity producing the most uniform temperature distribution. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7502 / 7514
页数:13
相关论文
共 50 条
  • [21] Gas Flow Sputtering of Catalyst Layers for Polymer Electrolyte Membrane Fuel Cells
    Vasic, Stanislav
    Guenther, Bernd H.
    CHEMIE INGENIEUR TECHNIK, 2012, 84 (12) : 2204 - 2209
  • [22] Optimization of gas diffusion media for elevated temperature polymer electrolyte fuel cells
    Sinha, Puneet K.
    Wang, Chao-Yang
    Su, Ay
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (07) : 886 - 894
  • [23] Gas crossover leakage in high temperature polymer electrolyte fuel cells: In situ quantification and effect on performance
    Galbiati, S.
    Baricci, A.
    Casalegno, A.
    Marchesi, R.
    JOURNAL OF POWER SOURCES, 2012, 205 : 350 - 353
  • [24] Effect of gas permeability in a porous flow channel on the cell current in a polymer electrolyte fuel cell (PEFC) system
    Lee, CS
    Yun, CH
    Kim, BM
    Jang, SC
    Yi, SC
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2005, 6 (02): : 188 - 195
  • [25] Self-heating characteristics of coal dust deposits by a hot gas flow in oxy-fuel atmospheres
    Wu, Dejian
    Norman, Frederik
    Vanierschot, Maarten
    Verplaetsen, Filip
    Berghmans, Jan
    APPLIED THERMAL ENGINEERING, 2018, 131 : 947 - 957
  • [26] Effect of anisotropic electrical resistivity of gas diffusion layers (GDLs) on current density and temperature distribution in a Polymer Electrolyte Membrane (PEM) fuel cell
    Bapat, Chaitanya J.
    Thynell, Stefan T.
    JOURNAL OF POWER SOURCES, 2008, 185 (01) : 428 - 432
  • [27] Study of flow channel geometry using current distribution measurement in a high temperature polymer electrolyte membrane fuel cell
    Lobato, Justo
    Canizares, Pablo
    Rodrigo, Manuel A.
    Javier Pinar, F.
    Ubeda, Diego
    JOURNAL OF POWER SOURCES, 2011, 196 (09) : 4209 - 4217
  • [28] Evaluation of the effect of reactant gases mass flow rates on power density in a polymer electrolyte membrane fuel cell
    Kahveci, E. E.
    Taymaz, I.
    2017 6TH INTERNATIONAL CONFERENCE ON POWER SCIENCE AND ENGINEERING (ICPSE 2017), 2018, 136
  • [29] Long-Term Testing of a High Temperature Polymer Electrolyte Membrane Fuel Cell: The Effect of Reactant Gases
    Pinar, F. Javier
    Pilinski, Nadine
    Wagner, Peter
    AICHE JOURNAL, 2016, 62 (01) : 217 - 227
  • [30] Current density distributions in polymer electrolyte fuel cells: A tool for characterisation of gas distribution in the cell and its state of health
    Belhadj, M.
    Aquino, A.
    Heng, J.
    Kmiotek, S.
    Rael, S.
    Bonnet, C.
    Lapicque, F.
    CHEMICAL ENGINEERING SCIENCE, 2018, 185 : 18 - 25