Effect of reactant gas flow orientation on the current and temperature distribution in self-heating polymer electrolyte fuel cells

被引:13
|
作者
Rasha, L. [1 ]
Cho, J. I. S. [1 ]
Millichamp, J. [1 ]
Neville, T. P. [1 ]
Shearing, P. R. [1 ]
Brett, D. J. L. [1 ]
机构
[1] UCL, Electrochem Innovat Lab, Dept Chem Engn, London WC1E 7JE, England
基金
英国工程与自然科学研究理事会;
关键词
Self-heating; Non-isothermal; Voltage recovery; Current distribution mapping; Temperature distribution mapping; Flow orientation;
D O I
10.1016/j.ijhydene.2020.11.223
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cell polarisation performance is typically reported under controlled/constant temperature conditions, as a sign of robust metrology. However, in practice, fuel cells self-heat as they generate current; which varies the temperature across the polarisation curve and affects performance. More detail regarding the internal cell operation can be gleaned by current and temperature distribution mapping. For the case of an unheated cell, 'self-heating' increases the cell temperature and improves performance, resulting in a 'voltage recovery' and a more homogeneous current and water distribution. For actively heated cells, a reduced current is observed in regions of high temperature and low humidity. The positioning of the gas manifolds also has a decisive impact on performance by affecting the reactant concentration, humidity and water distribution. Counter- and cross-flow orientations in a self-heating cell were studied, with a counter-flow orientation with air flowing with gravity producing the most uniform temperature distribution. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7502 / 7514
页数:13
相关论文
共 50 条
  • [1] The effect of pressure distribution on the gas flow in the polymer electrolyte fuel cell
    Kurihara, Eru
    Kumar, Saha Litan
    Oshima, Nobuyuki
    Nihon Kikai Gakkai Ronbunshu, B Hen/Transactions of the Japan Society of Mechanical Engineers, Part B, 2009, 75 (751): : 530 - 531
  • [2] On the temperature distribution in polymer electrolyte fuel cells
    Pharoah, J. G.
    Burheim, O. S.
    JOURNAL OF POWER SOURCES, 2010, 195 (16) : 5235 - 5245
  • [3] Nonuniform compensation of current density distribution in polymer electrolyte fuel cells by local heating
    Zhou, Shangwei
    Rasha, Lara
    Xu, Linlin
    Du, Wenjia
    Shearing, Paul. R.
    Coppens, Marc-Olivier
    Brett, Dan J. L.
    Jervis, Rhodri
    ENERGY CONVERSION AND MANAGEMENT, 2023, 297
  • [4] In situ current distribution measurements in polymer electrolyte fuel cells
    Mench, MM
    Wang, CY
    Ishikawa, M
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (08) : A1052 - A1059
  • [5] Water distribution in high temperature polymer electrolyte fuel cells
    Reimer, Uwe
    Ehlert, Jannik
    Janssen, Holger
    Lehnert, Werner
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (03) : 1837 - 1845
  • [6] Effect of gravity and gas flow direction on the operation of Polymer Electrolyte Membrane Fuel Cells
    Vinh Nguyen Duy
    Kim, Hyung-Man
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (12): : 11833 - 11854
  • [7] The influence of CO on the current density distribution of high temperature polymer electrolyte membrane fuel cells
    Boaventura, M.
    Sander, H.
    Friedrich, K. A.
    Mendes, A.
    ELECTROCHIMICA ACTA, 2011, 56 (25) : 9467 - 9475
  • [8] Experimental study on the effect of reactant flow arrangements on the current distribution in proton exchange membrane fuel cells
    Alaefour, I.
    Karimi, G.
    Jiao, Kui
    Al Shakhshir, S.
    Li, X.
    ELECTROCHIMICA ACTA, 2011, 56 (05) : 2591 - 2598
  • [9] Effect of ageing of gas diffusion layers on the water distribution in flow field channels of polymer electrolyte membrane fuel cells
    Kaetzel, Juliane
    Markoetter, Henning
    Arlt, Tobias
    Klages, Merle
    Haussmann, Jan
    Messerschmidt, Matthias
    Kardjilov, Nikolay
    Scholta, Joachim
    Banhart, John
    Manke, Ingo
    JOURNAL OF POWER SOURCES, 2016, 301 : 386 - 391
  • [10] Effect of fiber orientation on Liquid-Gas flow in the gas diffusion layer of a polymer electrolyte membrane fuel cell
    Lee, Seung-Hun
    Nam, Jin Hyun
    Kim, Charn-Jung
    Kim, Hyung Min
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (68) : 33957 - 33968