Ferrocene-Triazole Combination as a Benchmark for the Electrochemical Detection of Noncovalent Halogen-Bonding Interactions

被引：36
|
作者：
Zapata, Fabiola [1 ]
Caballero, Antonio [1 ]
Molina, Pedro [1 ]
机构：
[1] Univ Murcia, Dept Quim Organ, Campus Espinardo, E-30100 Murcia, Spain
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 02期
关键词：
Halogen bonding; Ferrocenes; Anions; Electrochemistry; Nitrogen heterocycles; STRUCTURAL-CHARACTERIZATION; SENSING PROPERTIES; CLICK CHEMISTRY; RECOGNITION; CATIONS; ANIONS; RECEPTORS; DERIVATIVES; MOLECULES; BEARING;
D O I：
10.1002/ejic.201600838
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and sensing properties of a triferrocene-bis(iodotriazole) are described. In general, halogen-bonding (XB) receptor 3 undergoes remarkable cathodic shifts of the two redox peaks in the presence of several oxoanions. These perturbations, which are attributable to noncovalent halogen-bonding interactions, are slightly smaller than those observed for the parent hydrogen-bonding (HB) receptor 4 with the same oxoanions.
引用
收藏
页码：237 / 241
页数：5
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