Ferrocene-Triazole Combination as a Benchmark for the Electrochemical Detection of Noncovalent Halogen-Bonding Interactions

被引：36

作者：

Zapata, Fabiola ^{[1
]}

Caballero, Antonio ^{[1
]}

Molina, Pedro ^{[1
]}

机构：

[1] Univ Murcia, Dept Quim Organ, Campus Espinardo, E-30100 Murcia, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 02期

关键词：

Halogen bonding; Ferrocenes; Anions; Electrochemistry; Nitrogen heterocycles; STRUCTURAL-CHARACTERIZATION; SENSING PROPERTIES; CLICK CHEMISTRY; RECOGNITION; CATIONS; ANIONS; RECEPTORS; DERIVATIVES; MOLECULES; BEARING;

D O I：

10.1002/ejic.201600838

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and sensing properties of a triferrocene-bis(iodotriazole) are described. In general, halogen-bonding (XB) receptor 3 undergoes remarkable cathodic shifts of the two redox peaks in the presence of several oxoanions. These perturbations, which are attributable to noncovalent halogen-bonding interactions, are slightly smaller than those observed for the parent hydrogen-bonding (HB) receptor 4 with the same oxoanions.

引用

页码：237 / 241

页数：5

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