New type of lariat ethers:: Synthesis and cation binding ability of phosphonoalkyl-azacrown ethers

被引：14

作者：

Keglevich, G ^{[1
]}

Novák, T

Bakó, P

Ujszászy, K

Ludányi, K

Tóth, K

Toke, L

机构：

[1] Tech Univ Budapest, Dept Organ Chem Technol, H-1521 Budapest, Hungary

[2] Eotvos Lorand Univ, Dept Gen & Inorgan Chem, H-1518 Budapest, Hungary

[3] Hungarian Acad Sci, Cent Res Inst Chem, H-1525 Budapest, Hungary

[4] Tech Univ Budapest, Inst Gen & Analyt Chem, H-1521 Budapest, Hungary

[5] Tech Univ Budapest, Hungarian Acad Sci, Res Grp, H-1521 Budapest, Hungary

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 1999年 / 34卷 / 03期

关键词：

azacrown ethers; lariat ethers; phosphonoalkyl side chain; extraction ability;

D O I：

10.1023/A:1008088112286

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of azacrown ethers with phosphonoalkyl side chains of two to five carbon atoms (3-8, 10), potentially useful as a new type of cation binding agent, is described. Introduction of the phosphonoalkyl moiety into the parent monoaza-15-crown-5 (1) decreases the cation extraction ability, but results in an increase in the selectivity towards the cations examined. The effect of the phosphonoalkyl-azacrown ethers on the properties of membranes used in ion-selective electrodes is also reported.

引用

页码：299 / 309

页数：11

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