New type of lariat ethers:: Synthesis and cation binding ability of phosphonoalkyl-azacrown ethers

被引：14
|
作者：
Keglevich, G [1 ]
Novák, T
Bakó, P
Ujszászy, K
Ludányi, K
Tóth, K
Toke, L
机构：
[1] Tech Univ Budapest, Dept Organ Chem Technol, H-1521 Budapest, Hungary
[2] Eotvos Lorand Univ, Dept Gen & Inorgan Chem, H-1518 Budapest, Hungary
[3] Hungarian Acad Sci, Cent Res Inst Chem, H-1525 Budapest, Hungary
[4] Tech Univ Budapest, Inst Gen & Analyt Chem, H-1521 Budapest, Hungary
[5] Tech Univ Budapest, Hungarian Acad Sci, Res Grp, H-1521 Budapest, Hungary
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 1999年 / 34卷 / 03期
关键词：
azacrown ethers; lariat ethers; phosphonoalkyl side chain; extraction ability;
D O I：
10.1023/A:1008088112286
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of azacrown ethers with phosphonoalkyl side chains of two to five carbon atoms (3-8, 10), potentially useful as a new type of cation binding agent, is described. Introduction of the phosphonoalkyl moiety into the parent monoaza-15-crown-5 (1) decreases the cation extraction ability, but results in an increase in the selectivity towards the cations examined. The effect of the phosphonoalkyl-azacrown ethers on the properties of membranes used in ion-selective electrodes is also reported.
引用
收藏
页码：299 / 309
页数：11
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