Two microporous CoII-MOFs with dual active sites for highly selective adsorption of CO2/CH4 and CO2/N2

被引:18
|
作者
Ma, Hui-Yan [1 ,2 ]
Zhang, Yong-Zheng [3 ]
Yan, Hui [1 ,2 ]
Zhang, Wen-Jie [1 ,2 ]
Li, Yun-Wu [1 ,2 ]
Wang, Su-Na [1 ,2 ]
Li, Da-Cheng [1 ,2 ]
Dou, Jian-Min [1 ,2 ]
Li, Jian-Rong [3 ]
机构
[1] Liaocheng Univ, Sch Mat Sci & Engn, Shandong Prov Key Lab, Collaborat Innovat Ctr Chem Energy Storage & Nove, Liaocheng 252000, Shandong, Peoples R China
[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Shandong, Peoples R China
[3] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; GAS-ADSORPTION; BUILDING-BLOCKS; EFFICIENT; SEPARATION; SORPTION; TOPOLOGY; CAPTURE; CH4;
D O I
10.1039/c9dt02694k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Simultaneously involving abundant [NH2(CH3)(2)](+) cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous Co-II-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N-2. GCMC theoretical simulations provide good verification of the experimental results.
引用
收藏
页码:13541 / 13545
页数:5
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