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Two microporous CoII-MOFs with dual active sites for highly selective adsorption of CO2/CH4 and CO2/N2
被引:18
|作者:
Ma, Hui-Yan
[1
,2
]
Zhang, Yong-Zheng
[3
]
Yan, Hui
[1
,2
]
Zhang, Wen-Jie
[1
,2
]
Li, Yun-Wu
[1
,2
]
Wang, Su-Na
[1
,2
]
Li, Da-Cheng
[1
,2
]
Dou, Jian-Min
[1
,2
]
Li, Jian-Rong
[3
]
机构:
[1] Liaocheng Univ, Sch Mat Sci & Engn, Shandong Prov Key Lab, Collaborat Innovat Ctr Chem Energy Storage & Nove, Liaocheng 252000, Shandong, Peoples R China
[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Shandong, Peoples R China
[3] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
关键词:
METAL-ORGANIC FRAMEWORKS;
CARBON-DIOXIDE;
GAS-ADSORPTION;
BUILDING-BLOCKS;
EFFICIENT;
SEPARATION;
SORPTION;
TOPOLOGY;
CAPTURE;
CH4;
D O I:
10.1039/c9dt02694k
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Simultaneously involving abundant [NH2(CH3)(2)](+) cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous Co-II-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N-2. GCMC theoretical simulations provide good verification of the experimental results.
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页码:13541 / 13545
页数:5
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