Two microporous CoII-MOFs with dual active sites for highly selective adsorption of CO2/CH4 and CO2/N2

被引：18

作者：

Ma, Hui-Yan ^{[1
,2
]}

Zhang, Yong-Zheng ^{[3
]}

Yan, Hui ^{[1
,2
]}

Zhang, Wen-Jie ^{[1
,2
]}

Li, Yun-Wu ^{[1
,2
]}

Wang, Su-Na ^{[1
,2
]}

Li, Da-Cheng ^{[1
,2
]}

Dou, Jian-Min ^{[1
,2
]}

Li, Jian-Rong ^{[3
]}

机构：

[1] Liaocheng Univ, Sch Mat Sci & Engn, Shandong Prov Key Lab, Collaborat Innovat Ctr Chem Energy Storage & Nove, Liaocheng 252000, Shandong, Peoples R China

[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Shandong, Peoples R China

[3] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 36期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; GAS-ADSORPTION; BUILDING-BLOCKS; EFFICIENT; SEPARATION; SORPTION; TOPOLOGY; CAPTURE; CH4;

D O I：

10.1039/c9dt02694k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simultaneously involving abundant [NH2(CH3)(2)](+) cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous Co-II-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N-2. GCMC theoretical simulations provide good verification of the experimental results.

引用

页码：13541 / 13545

页数：5

共 50 条

[31] Adsorption Equilibrium of N2, CH4, and CO2 on MIL-101
Zhang, Yu
Su, Wei
Sun, Yan
Liu, Jia
Liu, Xiuwu
Wang, Xiaojing
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (10): : 2951 - 2957
[32] Adsorption of CH4/CO2/N2 by different functional groups in coal
Jia, Jinzhang
Wu, Yumo
Zhao, Dan
Li, Bin
Wang, Dongming
Wang, Fengxiao
FUEL, 2023, 335
[33] Molecular simulation of CO2/N2 injection on CH4 adsorption and diffusion
Li, Ziwen
Hu, Hongqing
Wang, Yinji
Gao, Yabin
Yan, Fazhi
Bai, Yansong
Yu, Hongjin
SCIENTIFIC REPORTS, 2024, 14 (01):
[34] Adsorption of CO2, CH4, and N2 in Activated Carbon Honeycomb Monolith
Ribeiro, Rui P. P. L.
Sauer, Ticiane P.
Lopes, Filipe V.
Moreira, Regina F.
Grande, Carlos A.
Rodrigues, Alirio E.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (10): : 2311 - 2317
[35] Simulation study of competitive adsorption of CH4/CO2 and CH4/N2 in anthracite coal
Bai, Gang
Zhang, Haijing
Zhang, Xun
Fan, Chaojun
Wang, Jue
Wei, Jie
Zhang, Yilong
ENERGY REPORTS, 2024, 12 : 6082 - 6092
[36] Adsorption of CO2, CO, CH4 and N2 on DABCO based metal organic frameworks
Mishra, Prashant
Edubilli, Satyannarayana
Mandal, Bishnupada
Gumma, Sasidhar
MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 169 : 75 - 80
[37] Adsorption of CO2, CO, CH4 and N2 on a zinc based metal organic framework
Mishra, Prashant
Mekala, Samuel
Dreisbach, Freider
Mandal, Bishnupada
Gumma, Sasidhar
SEPARATION AND PURIFICATION TECHNOLOGY, 2012, 94 : 124 - 130
[38] Volumetric Adsorption Measurements of N2, CO2, CH4, and a CO2 + CH4 Mixture on a Natural Chabazite from (5 to 3000) kPa
Watson, Guillaume C.
Jensen, Nathan K.
Rufford, Thomas E.
Chan, K. Ida
May, Eric F.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (01): : 93 - 101
[39] Targeted synthesis of novel porous aromatic frameworks with selective separation of CO2/CH4 and CO2/N2
Wang, Wei
Yuan, Ye
Sun, Fu-Xing
Zhu, Guang-Shan
CHINESE CHEMICAL LETTERS, 2014, 25 (11) : 1407 - 1410
[40] Dissociation enthalpies and phase equilibrium for TBAB semi-clathrate hydrates of N2, CO2, N2 + CO2 and CH4 + CO2
Johnny Deschamps
Didier Dalmazzone
Journal of Thermal Analysis and Calorimetry, 2009, 98 : 113 - 118

← 1 2 3 4 5 →