Two microporous CoII-MOFs with dual active sites for highly selective adsorption of CO2/CH4 and CO2/N2

被引：18

作者：

Ma, Hui-Yan ^{[1
,2
]}

Zhang, Yong-Zheng ^{[3
]}

Yan, Hui ^{[1
,2
]}

Zhang, Wen-Jie ^{[1
,2
]}

Li, Yun-Wu ^{[1
,2
]}

Wang, Su-Na ^{[1
,2
]}

Li, Da-Cheng ^{[1
,2
]}

Dou, Jian-Min ^{[1
,2
]}

Li, Jian-Rong ^{[3
]}

机构：

[1] Liaocheng Univ, Sch Mat Sci & Engn, Shandong Prov Key Lab, Collaborat Innovat Ctr Chem Energy Storage & Nove, Liaocheng 252000, Shandong, Peoples R China

[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Shandong, Peoples R China

[3] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 36期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; GAS-ADSORPTION; BUILDING-BLOCKS; EFFICIENT; SEPARATION; SORPTION; TOPOLOGY; CAPTURE; CH4;

D O I：

10.1039/c9dt02694k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simultaneously involving abundant [NH2(CH3)(2)](+) cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous Co-II-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N-2. GCMC theoretical simulations provide good verification of the experimental results.

引用

页码：13541 / 13545

页数：5

共 50 条

[1] Adsorption CO2, CH4 and N2 on two different spacing flexible layer MOFs
Yang, Jiangfeng
Yu, Qiuhong
Zhao, Qiang
Liang, Jianming
Dong, Jinxiang
Li, Jinping
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 161 : 154 - 159
[2] Sustainable nanoporous carbon for CO2, CH4, N2, H2 adsorption and CO2/CH4 and CO2/N2 separation
Park, Jaewoo
Attia, Nour F.
Jung, Minji
Lee, Myoung Eun
Lee, Kiyoung
Chung, Jaewoo
Oh, Hyunchul
ENERGY, 2018, 158 : 9 - 16
[3] Highly enhanced and weakened adsorption properties of two MOFs by water vapor for separation of CO2/CH4 and CO2/N2 binary mixtures
Xian, Shikai
Peng, Junjie
Zhang, Zhijuan
Xia, Qibin
Wang, Haihui
Li, Zhong
CHEMICAL ENGINEERING JOURNAL, 2015, 270 : 385 - 392
[4] Highly enhanced and weakened adsorption properties of two MOFs by water vapor for separation of CO2/CH4 and CO2/N2 binary mixtures
Xian, Shikai
Peng, Junjie
Zhang, Zhijuan
Xia, Qibin
Wang, Haihui
Li, Zhong
Chemical Engineering Journal, 2015, 270 : 385 - 392
[5] Adsorption of CO2, CH4, CO2/N2 and CO2/CH4 in Novel Activated Carbon Beads: Preparation, Measurements and Simulation
Shao, Xiaohong
Feng, Zhenhe
Xue, Ruisheng
Ma, Congcong
Wang, Wenchuan
Peng, Xuan
Cao, Dapeng
AICHE JOURNAL, 2011, 57 (11) : 3042 - 3051
[6] Molecular Simulations of CO2/CH4, CO2/N2 and N2/CH4 Binary Mixed Hydrates
A. A. Sizova
S. A. Grintsevich
M. A. Kochurin
V. V. Sizov
E. N. Brodskaya
Colloid Journal, 2021, 83 : 372 - 378
[7] Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4, and CH4/N2 by ZIFs
Liu, Bei
Smit, Berend
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (18): : 8515 - 8522
[8] Molecular Simulations of CO2/CH4, CO2/N2 and N2/CH4 Binary Mixed Hydrates
Sizova, A. A.
Grintsevich, S. A.
Kochurin, M. A.
Sizov, V. V.
Brodskaya, E. N.
COLLOID JOURNAL, 2021, 83 (03) : 372 - 378
[9] A 3D Ba-MOF for selective adsorption of CO2/CH4 and CO2/N2
Xiaokang Wang
Yutong Wang
Kebin Lu
Weiteng Jiang
Fangna Dai
ChineseChemicalLetters, 2021, 32 (03) : 1169 - 1172
[10] A 3D Ba-MOF for selective adsorption of CO2/CH4 and CO2/N2
Wang, Xiaokang
Wang, Yutong
Lu, Kebin
Jiang, Weifeng
Dai, Fangna
CHINESE CHEMICAL LETTERS, 2021, 32 (03) : 1169 - 1172

← 1 2 3 4 5 →