High-Branched Organosilicon Epoxy Resin with Low Viscosity, Excellent Toughness, Hydrophobicity, and Dielectric Property

被引:7
|
作者
Yu, Min [1 ]
Chen, Zeyuan [1 ]
Li, Jie [1 ]
Tan, Jihuai [1 ]
Zhu, Xinbao [1 ,2 ]
机构
[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Nanjing 210037, Peoples R China
[2] Anhui Engn Res Ctr Epoxy Resin & Addit, Huangshan 245900, Peoples R China
来源
MOLECULES | 2023年 / 28卷 / 06期
基金
中国国家自然科学基金;
关键词
silicone resins; viscosity reduction; toughening; hydrophobicity; dielectric properties; FLAME-RETARDANT;
D O I
10.3390/molecules28062826
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Rapidly developing technology places higher demands on materials, thus the simultaneous improvement of materials' multiple properties is a hot research topic. In this work, a high-branched silicone epoxy resin (QSiE) was synthesized and applied to the curing system of bisphenol A epoxy resin (DGEBA) for modification investigations. When 6 wt% QSiE was added to the system, the viscosity dropped by 51.8%. The mechanical property testing results indicated that QSiE could significantly enhance the material's toughness while preserving good rigidity. The impact strength was enhanced by 1.31 times when 6wt% of QSiE was introduced. Additionally, the silicon skeleton in QSiE has low surface energy and low polarizability, which could endow the material with good hydrophobic and dielectric properties. This work provided a new idea for the preparation of high-performance epoxy resin additives, and provided a broad prospect for cutting-edge applications of epoxy resins.
引用
收藏
页数:12
相关论文
共 50 条
  • [41] Improved High-temperature Dielectric Property of Epoxy Resin Composites with Nano- and Micro-sized Magnesia Fillers
    Xie, Q.
    Ohki, Y.
    Hirai, N.
    Cheng, Y-H
    2017 IEEE INTERNATIONAL WORKSHOP ON INTEGRATED POWER PACKAGING (IWIPP), 2017,
  • [42] Effects of Thermo-Oxidative Aging on the Dielectric Property and Electrical Breakdown of Epoxy Resin Using in High-Voltage Equipment
    Kong, Xiaoxiao
    Zhang, Chong
    Du, H. S.
    Miyake, H.
    Tanaka, Y.
    Du, Boxue
    IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2025, 32 (01) : 254 - 262
  • [43] One-pot solvent-free synthesis of self-catalyzed phosphorus/silicon cycloaliphatic epoxy resin with excellent flame-retardant and dielectric property
    Lv, Yonghao
    Li, Hongyan
    Shao, Zhu-Bao
    Jiang, Zhiming
    POLYMER, 2025, 320
  • [44] Improved Cyanate Resin with Low Dielectric Constant and High Toughness Prepared Using Inorganic-Organic Hybrid Porous Silica
    Wu, Zhenzhen
    Zhao, Li-zhen
    Qi, Lu
    Jiao, Jian
    CHEMISTRY LETTERS, 2017, 46 (01) : 139 - 142
  • [45] High performance epoxy resin composites modified with multifunctional thiophene/phosphaphenanthrene-based flame retardant: Excellent flame retardance, strong mechanical property and high transparency
    Wang, Hao
    Yuan, Jun
    Zhu, Zongmin
    Yin, Xianze
    Weng, Yunxuan
    Wang, Zhaojia
    Yang, Feihua
    Zhan, Jiayu
    Wang, Hua
    Wang, Luoxin
    Composites Part B: Engineering, 2021, 227
  • [46] High performance epoxy resin composites modified with multifunctional thiophene/phosphaphenanthrene-based flame retardant: Excellent flame retardance, strong mechanical property and high transparency
    Wang, Hao
    Yuan, Jun
    Zhu, Zongmin
    Yin, Xianze
    Weng, Yunxuan
    Wang, Zhaojia
    Yang, Feihua
    Zhan, Jiayu
    Wang, Hua
    Wang, Luoxin
    COMPOSITES PART B-ENGINEERING, 2021, 227
  • [47] Low-cost and facile fabrication of titanium dioxide coated oxidized titanium diboride-epoxy resin composites with high dielectric constant and extremely low dielectric loss
    Gu, Longcheng
    Wang, Tongxing
    Zhang, Wei
    Liang, Guozheng
    Gu, Aijuan
    Yuan, Li
    RSC ADVANCES, 2013, 3 (19) : 7071 - 7082
  • [48] Synthesis of pyrogallol triglycidyl ether: A bio-based epoxy resin monomer with low viscosity, high activity, and good thermomechanical properties
    Long, Yu
    Han, Weihua
    Xing, Zhaoliang
    Hao, Chuncheng
    POLYMER, 2024, 297
  • [49] High-performance shape memory epoxy resin with high strength and toughness: Prepared by introducing hydrogen bonds through polycaprolactone and low melting point alloy
    Tuo, Zhiwei
    Chen, Kunzhi
    Zhou, Qiang
    Wang, Yubo
    Wang, Qiushi
    Zhang, Yuyu
    Lin, Zhaohua
    Liang, Yunhong
    COMPOSITES SCIENCE AND TECHNOLOGY, 2024, 250
  • [50] A micromechanical model of elastic-damage properties of innovative pothole patching materials featuring high-toughness, low-viscosity nanomolecular resin
    Zhang, H.
    Ju, J. Woody
    Zhu, W. L.
    Yuan, K. Y.
    INTERNATIONAL JOURNAL OF DAMAGE MECHANICS, 2021, 30 (09) : 1327 - 1350