High-Branched Organosilicon Epoxy Resin with Low Viscosity, Excellent Toughness, Hydrophobicity, and Dielectric Property

被引:7
|
作者
Yu, Min [1 ]
Chen, Zeyuan [1 ]
Li, Jie [1 ]
Tan, Jihuai [1 ]
Zhu, Xinbao [1 ,2 ]
机构
[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Nanjing 210037, Peoples R China
[2] Anhui Engn Res Ctr Epoxy Resin & Addit, Huangshan 245900, Peoples R China
来源
MOLECULES | 2023年 / 28卷 / 06期
基金
中国国家自然科学基金;
关键词
silicone resins; viscosity reduction; toughening; hydrophobicity; dielectric properties; FLAME-RETARDANT;
D O I
10.3390/molecules28062826
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Rapidly developing technology places higher demands on materials, thus the simultaneous improvement of materials' multiple properties is a hot research topic. In this work, a high-branched silicone epoxy resin (QSiE) was synthesized and applied to the curing system of bisphenol A epoxy resin (DGEBA) for modification investigations. When 6 wt% QSiE was added to the system, the viscosity dropped by 51.8%. The mechanical property testing results indicated that QSiE could significantly enhance the material's toughness while preserving good rigidity. The impact strength was enhanced by 1.31 times when 6wt% of QSiE was introduced. Additionally, the silicon skeleton in QSiE has low surface energy and low polarizability, which could endow the material with good hydrophobic and dielectric properties. This work provided a new idea for the preparation of high-performance epoxy resin additives, and provided a broad prospect for cutting-edge applications of epoxy resins.
引用
收藏
页数:12
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